Nanocrystal/Metal–Organic Framework Hybrids as Electrocatalytic Platforms for CO2 Conversion
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This thesis deals with the electrocatalytic properties of two-dimensional metal organic coordination networks (2D-MOCNs) self-assembled on electrode surfaces and catalytic activity of 2D-MOCNs is demonstrated for the first time. The low-coordinated metal c ...
Metal organic supramolecular chemistry on surfaces has matured to a point where its underlying growth mechanisms are well understood and structures of defined coordination environments of metal atoms can be synthesized in a controlled and reproducible proc ...
In Nature, many vital biological processes take place across the interface formed between two dielectric media. For instance, photosynthesis and aerobic respiration involve a series of redox reactions occurring across energy-transducing membranes, in charg ...
This thesis is concerned with supramolecular architectures assembled at metal surfaces. The investigations pursued two objectives. On the one hand, the focus was placed on the fabrication of low-dimensional surface-supported network structures by applying ...
Controlled mixtures of novel Mg-based metal-organic frameworks (MOFs) were prepared, with H+ or K+ as counterions. A linear relation was found between synthesis pH and K/H ratio in the resultant mixture, establishing the tunability of the synthesis. Upon p ...
Metal-organic frameworks (MOFs), a class of porous materials, are of particular interest in gas storage and separation applications due largely to their high internal surface areas and tunable structures. MOF-5 is perhaps the archetypal MOF; in particular, ...
We report a one-step synthetic strategy to encapsulate copper nanocrystals (Cu NCs) in a carboxylate-based metal organic framework (MOF-74) to construct Cu@Cu-MOF-74 hybrids. One of the hurdles to realizing metal NC@MOF hybrids with uniform morphology and ...
The hydrogen storage properties of a new family of isostructural metal organic frameworks are reported. The frameworks M-2(dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn; dobpdc(4-) = 4,4'-dioxidobiphenyl-3,3'-dicarboxylate) are analogous to the widely studied M-2(do ...
Materials exhibiting reversible hydrogen adsorption with high gravimetric and volumetric capacities are sought for use in on-board storage systems of hydrogen fuel cell-powered vehicles. Microporous metal-org. frameworks with high internal surface areas ha ...
This Feature Article reports on the controlled formation and structure-functionality aspects of vacuum-deposited self-assembled organic and metal-organic networks at metal surfaces using ditopic linear and nonlinear molecular bricks, namely di-carbonitrile ...