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Cryogel 3d scaffolds and methods for producing thereof

Related publications (48)

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High-temperature radical polymerization of methyl methacrylate in a continuous pilot scale process

Philip Nising

The present PhD thesis deals with the high temperature polymerization of methyl methacrylate in a continuous pilot scale process. The major aim is to investigate the feasibility of a polymerization process for the production of PMMA molding compound at tem ...

EPFL2006

Reaction calorimetry in supercritical fluids

Sophie Fortini

This thesis is devoted to the study of the dispersion polymerization of methyl methacrylate in supercritical carbon dioxide (scCO2), using a poly(dimethylsiloxane) macromonomer (PDMS macromonomer) as stabilizer. Supercritical fluids (SCF) and SCF mixtures ...

EPFL2006

Solid-state structure, organization and properties of peptide-synthetic hybrid block copolymers

Harm-Anton Klok

Peptide-synthetic hybrid block copolymers are most easily prepared via ring-opening polymerization of ?-amino acid N-carboxyanhydrides using appropriately end-functionalized synthetic polymers as the macroinitiator. This class of peptide-synthetic hybrid b ...

2006

Molecular Imprinting with Ruthenium Porphyrin Catalysts

Kay Severin, Estelle Burri

A ruthenium meso-tetra[4-(vinylbenzoxy)benzyl]porphyrin catalyst with four polymerizable side chains was synthesized in three steps from commercially available starting materials. The polymerizable side chains allowed the incorporation of this complex in h ...

2006

Synthesis and characterization of thermoresponsive polymers, hydrogels and microgels, based on poly(N-substituted acrylamides)

Stimuli-responsive polymers have the unique property of undergoing a reversible phase transition. This property has attracted much interest for their application in the field of medicine and biotechnology, such as drug delivery systems. Linear polymers of ...

EPFL2004

Synthesis and Optical Properties of Water-Soluble NIR Absorbing Star Polypeptides based on Functional Rylene Dyes

Harm-Anton Klok

In this contribution, the synthesis of two novel amino-functionalized terrylene and quaterrylene diimide derivatives is described. These chromophores have been used as initiators for the ring-opening polymerization of N€-benzyloxycarbonyl-L-lysine N-carbox ...

Springer, Springer-Verlag2004

Synthesis and optical properties of water-soluble NIR absorbing star polypeptides based on functional rylene dyes

Harm-Anton Klok

2004

Highly branched poly(L-lysine)

Harm-Anton Klok

This paper describes the synthesis of several novel water-soluble highly branched polypeptides. The synthesis starts with the ring-opening polymerization of ε-benzyloxycarbonyl-L-lysine N-carboxyanhydride (Z-Lys NCA) or ε-trifluoroacetyl-L-lysine N-carboxy ...

2003

Dendritic-graft polypeptides

Harm-Anton Klok

A new synthetic strategy for the preparation of highly branched, or dendritic-graft, polypeptides is presented. The synthetic strategy is based on a repetitive sequence of ring-opening copolymerization and deprotection steps. Comonomers for the ring-openin ...

2002

Catalysis in prebiotic chemistry: Steps towards the RNA world

It is proposed that catalysis by minerals and metal ions had a central role in the steps that led to the origins of life. In particular, the formation of biopolymers in the presence of water requires catalysis to compete with hydrolytic reactions. Catalysi ...

2002