68–95–99.7 ruleIn statistics, the 68–95–99.7 rule, also known as the empirical rule, is a shorthand used to remember the percentage of values that lie within an interval estimate in a normal distribution: 68%, 95%, and 99.7% of the values lie within one, two, and three standard deviations of the mean, respectively. In mathematical notation, these facts can be expressed as follows, where Pr() is the probability function, Χ is an observation from a normally distributed random variable, μ (mu) is the mean of the distribution, and σ (sigma) is its standard deviation: The usefulness of this heuristic especially depends on the question under consideration.
Mass spectrometryMass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a mass spectrum, a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures. A mass spectrum is a type of plot of the ion signal as a function of the mass-to-charge ratio.
