Pi backbondingIn chemistry, π backbonding, also called π backdonation, is when electrons move from an atomic orbital on one atom to an appropriate symmetry antibonding orbital on a π-acceptor ligand. It is especially common in the organometallic chemistry of transition metals with multi-atomic ligands such as carbon monoxide, ethylene or the nitrosonium cation. Electrons from the metal are used to bond to the ligand, in the process relieving the metal of excess negative charge. Compounds where π backbonding occurs include Ni(CO)4 and Zeise's salt.
Organophosphorus chemistryOrganophosphorus chemistry is the scientific study of the synthesis and properties of organophosphorus compounds, which are organic compounds containing phosphorus. They are used primarily in pest control as an alternative to chlorinated hydrocarbons that persist in the environment. Some organophosphorus compounds are highly effective insecticides, although some are extremely toxic to humans, including sarin and VX nerve agents. Phosphorus, like nitrogen, is in group 15 of the periodic table, and thus phosphorus compounds and nitrogen compounds have many similar properties.
PicoplanktonPicoplankton is the fraction of plankton composed by cells between 0.2 and 2 μm that can be either prokaryotic and eukaryotic phototrophs and heterotrophs: photosynthetic Photosynthetic picoplankton heterotrophic Heterotrophic picoplankton They are prevalent amongst microbial plankton communities of both freshwater and marine ecosystems. They have an important role in making up a significant portion of the total biomass of phytoplankton communities. In general, plankton can be categorized on the basis of physiological, taxonomic, or dimensional characteristics.
Redfield ratioThe Redfield ratio or Redfield stoichiometry is the consistent atomic ratio of carbon, nitrogen and phosphorus found in marine phytoplankton and throughout the deep oceans. The term is named for American oceanographer Alfred C. Redfield who in 1934 first described the relatively consistent ratio of nutrients in marine biomass samples collected across several voyages on board the research vessel Atlantis, and empirically found the ratio to be C:N:P = 106:16:1.
