Archetypal Soft-Mode-Driven Antipolar Transition in Francisite Cu3Bi(SeO3)(2)O2Cl
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We introduce a minimal model describing the physics of classical two-dimensional (2D) frustrated Heisenberg systems, where spins order in a nonplanar way at T=0. This model, consisting of coupled trihedra (or Ising-RP3 model), encompasses Ising (chiral) de ...
The thermal decomposition of three synthetic copper sulfides (chalcocite (Cu2S), chalcopyrite (CuFeS2), and enargite (Cu3AsS4)) and two commercial copper concentrates has been studied on a thermobalance (T = 1173-1773 K) and an imaging furnace (T approxima ...
A combined synchrotron X-ray diffraction, Raman scattering, and infrared spectroscopy study of the pressure-induced changes in H3BO3 to 10 GPa revealed a new high-pressure phase transition between 1 and 2 GPa followed by chemical decomposition into cubic H ...
Strontium barium niobate (SrxBa1-xNb2O6, shortly SBN) is a solid solution system with tetragonal tungsten bronze crystal structure. It exhibits a ferroelectric phase with only one polar axis and a transition temperature depending on the Sr/Ba ratio. This t ...
Phase transitions in micro-, submicro-, and nanocrystalline NaNbO3 were investigated by temperature-tuning Raman spectroscopy and X-ray powder diffraction method. Three powders with different average particle size showed successive phase transitions within ...
We study proton diffusion in amorphous SiO2 from the atomic scale to the long-range percolative regime. Ab initio molecular dynamics suggest that the dominant atomic process consists in cross-ring interoxygen hopping assisted by network vibrations. A stati ...
We report the results of a low-temperature (300 K-15 K) high-pressure (up to 22 GPa) Raman study of the Verwey transition in magnetite (Fe3O4). We use additional Raman modes observed below the Verwey transition to determine how the transition temperature c ...
We report Raman spectroscopy in all four phases of a (K0.5+delta Na0.5-delta)NbO3 (delta similar to 0.03) crystal and ((K0.5+delta Na0.5-delta)(1-x)Li-x)NbO3 for x=0.02 and 0.03. The phase transitions in the Li-free crystal are homogeneous and hysteretic, ...
A detailed investigation of the electrical resistivity of a series of monovalent (Ag) doped polycrystalline La1−xAgxMnO3 pellets with x ranging from 0.05 to 0.30 and measured over the temperature range between 10 and 350 K is reported. La1−xAgxMnO3 compoun ...
The infrared reflectance of the transition-metal chalcogenide 1T-TaS2 has been measured at temperatures from 30 K to 360 K over 30-45 000 cm(-1) (4 meV-5.5 eV). The optical conductivity was obtained by Kramers-Kronig analysis. At 360 K only modest traces o ...