Enantioselective C-H Bond Functionalizations by 3d Transition-Metal Catalysts
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Supported metal catalysts are important from both an industrial and a scientific point of view. They are used, amongst others, in large-scale processes such as catalytic reforming, hydrotreating, polymerization reactions and hydrogenations. Often, these ca ...
Many low oxidation state transition metal (carbonyl) clusters are salts and are highly soluble in ionic liquids. Since many are also effective catalysts/precatalysts for hydrogenation reactions, we have conducted a catalytic study of these compounds in ion ...
Homo- and heterobimetallic complexes of the late transitions metals have been synthesized by metathesis reactions of the corresponding chloro-bridged dimers. These reactions have the advantage of being fast and giving rise to structurally defined products ...
A review. In an effort to develop new tripodal N-heterocyclic carbene (NHC) ligands for small mol. activation, two new classes of tripodal NHC ligands TIMER and TIMENR were synthesized. The C-anchored tris(carbene) ligand system TIMER (R = Me, t-Bu) forms ...
With the discovery of important biological roles of carbon monoxide (CO), the use of this gas as a therapeutic agent has attracted attention. However, the medical application of this gas has been hampered by the complexity of the administration method. To ...
New methods that allow the generation of transition metal-based catalysts and receptors are discussed. It is shown that heterobimetallic, halogeno-bridged complexes are well-suited for screening assays in combinatorial catalysis. Metal catalysts with a str ...
The nature of the bonding in ethylene and h2-P4 complexes, M(C2H4)2+ and M(h2-P4)2+, of group 11 metal cations (M = Cu, Ag, Au) has been explored by d. functional calcns. On the basis of the evaluation of symmetry orbitals, the contributions from the inter ...
Organophosphorus compounds found applications in varied fields of the organic chemistry: they are particularly present in natural compounds such as the deoxyribonucleic acid (DNA) and in the field of catalysis in which their utility is also proven. Thus, t ...
Structured supported ionic liquid-phase (SSILP) catalysis is a new concept with the advantages of ionic liquids (ILs) used as solvents for homogeneous catalyst and the further benefits of structured heterogeneous catalysts. This is achieved by confining th ...
This review seeks to evaluate the role of low oxidation state transition metal clusters (metal carbonyl clusters) in catalysis. The review commences with a discussion of the cluster surface analogy and then proceeds to discuss whether catalysis takes place ...