Perspective-Electrochemical Stability of Water-in-Salt Electrolytes
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This paper describes the anodic oxidn. of various aliph. alcs. in pure water using a Nafion cation exchange membrane as a solid polymer electrolyte. The oxidn. was carried out on an IrO2 anode under conditions of simultaneous O2 evolution. The exptl. resul ...
The common technology for solid oxide fuel cells (SOFC) is based on a cermet anode of nickel with yttrium stabilized zirconia (YSZ), often used as the supporting structure. One of the main limitations of this anode technology is the redox tolerance. In thi ...
The electrochem. oxidn. of benzoic acid (BA) was studied on boron-doped diamond electrodes on acid medium by cyclic voltammetry and bulk electrolysis. In the potential region where the supporting electrolyte is stable, reactions occur, resulting in the los ...
Adsorption isotherms of carboxylate type superplasticizers with different architectures have been measured on MgO considered as a non-reactive model powder. This system allowed us to study the influence of pH, electrolyte type, concentration and ionic stre ...
A comprehensive theoretical basis for understanding electrowetting is now available. It shows that it is possible to effect drastic shape changes in electrolyte droplets immersed in another (immiscible) electrolyte. ...
Due to their high efficiencies and their potentially low production costs, dye-sensitized solar cells (DSSC) have attracted much attention during the last few years. The technology is based on a layer made of mesoscopic TiO2 film which significantly increa ...
A SOFC, with a solid electrolyte layer and at least one anode layer constituting a stratified structure. The anode layer incorporates a twice substituted lanthanide chromite, substituted by Sr on A sites and by Ni or Cu on B sites. The stratified structure ...
A high power density and high capacity primary or secondary electrochemical generator in which at least one electrode (1,2) is composed of an electrically active solid material, said electrode having a mesoporous texture forming a bicontinuous junction of ...
Recent progress made in our lab. in the field of electrochem. promotion of heterogeneous catalytic gas reactions is reviewed. The phenomenon consists of electrochem. polarization of the catalyst/solid electrolyte interface resulting in a dramatic, non-Fara ...
The capacitance of monolayer-protected gold nanoclusters (MPCs), CMPC, in solution has been theoretically reconsidered from an electrostatic viewpoint, in which an MPC is considered as an isolated charged sphere within two dielectric layers, the intrinsic ...