Syn and anti additionIn organic chemistry, syn- and anti-addition are different ways in which substituent molecules can be added to an alkene () or alkyne (). The concepts of syn and anti addition are used to characterize the different reactions of organic chemistry by reflecting the stereochemistry of the products in a reaction. The type of addition that occurs depends on multiple different factors of a reaction, and is defined by the final orientation of the substituents on the parent molecule.
SI derived unitSI derived units are units of measurement derived from the seven SI base unit specified by the International System of Units (SI). They can be expressed as a product (or ratio) of one or more of the base units, possibly scaled by an appropriate power of exponentiation (see: Buckingham π theorem). Some are dimensionless, as when the units cancel out in ratios of like quantities.
Cheletropic reactionIn organic chemistry, cheletropic reactions, also known as chelotropic reactions, are a type of pericyclic reaction (a chemical reaction that involves a transition state with a cyclic array of atoms and an associated cyclic array of interacting orbitals). Specifically, cheletropic reactions are a subclass of cycloadditions. The key distinguishing feature of cheletropic reactions is that on one of the reagents, both new bonds are being made to the same atom. In the pericyclic transition state, a small molecule donates two electrons to the ring.
IUPAC nomenclature of organic chemistryIn chemical nomenclature, the IUPAC nomenclature of organic chemistry is a method of naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). It is published in the Nomenclature of Organic Chemistry (informally called the Blue Book). Ideally, every possible organic compound should have a name from which an unambiguous structural formula can be created. There is also an IUPAC nomenclature of inorganic chemistry.
Space tetherSpace tethers are long cables which can be used for propulsion, momentum exchange, stabilization and attitude control, or maintaining the relative positions of the components of a large dispersed satellite/spacecraft sensor system. Depending on the mission objectives and altitude, spaceflight using this form of spacecraft propulsion is theorized to be significantly less expensive than spaceflight using rocket engines. Tether satellites might be used for various purposes, including research into tether propulsion, tidal stabilization and orbital plasma dynamics.
HemiaminalIn organic chemistry, a hemiaminal (also carbinolamine) is a functional group or type of chemical compound that has a hydroxyl group and an amine attached to the same carbon atom: . R can be hydrogen or an alkyl group. Hemiaminals are intermediates in imine formation from an amine and a carbonyl by alkylimino-de-oxo-bisubstitution. Hemiaminals can be viewed as a blend of aminals and geminal diol. They are a special case of amino alcohols. The adducts formed by the addition of ammonia to aldehydes have long been studied.
Barbier reactionThe Barbier reaction is an organometallic reaction between an alkyl halide (chloride, bromide, iodide), a carbonyl group and a metal. The reaction can be performed using magnesium, aluminium, zinc, indium, tin, samarium, barium or their salts. The reaction product is a primary, secondary or tertiary alcohol. The reaction is similar to the Grignard reaction but the crucial difference is that the organometallic species in the Barbier reaction is generated in situ, whereas a Grignard reagent is prepared separately before addition of the carbonyl compound.
Interplanetary spaceflightInterplanetary spaceflight or interplanetary travel is the crewed or uncrewed travel between stars and planets, usually within a single planetary system. In practice, spaceflights of this type are confined to travel between the planets of the Solar System. Uncrewed space probes have flown to all the observed planets in the Solar System as well as to dwarf planets Pluto and Ceres, and several asteroids. Orbiters and landers return more information than fly-by missions.
KetosisKetosis is a metabolic state characterized by elevated levels of ketone bodies in the blood or urine. Physiological ketosis is a normal response to low glucose availability, such as low-carbohydrate diets or fasting, that provides an additional energy source for the brain in the form of ketones. In physiological ketosis, ketones in the blood are elevated above baseline levels, but the body's acid–base homeostasis is maintained.
Coherence (units of measurement)A coherent system of units is a system of units of measurement used to express physical quantities that are defined in such a way that the equations relating the numerical values expressed in the units of the system have exactly the same form, including numerical factors, as the corresponding equations directly relating the quantities. It is a system in which every quantity has a unique unit, or one that does not use conversion factors.
