Accessing the plus IV Oxidation State in Molecular Complexes of Praseodymium
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The synthesis of the first π-extended tetrathiafulvalene (TTF) ligand featuring a furanoquinonoid spacer and pyridyl functional groups is described. This compound shows an unprecedented electrochemical sensing behavior and excellent coordinating properties ...
The first solid-state structures of complexed P3N3X6 (X=halogen) are reported for X=Cl. The compounds were obtained from P3N3Cl6 and Ag[Al(OR)4] salts in CH2Cl2/CS2 solution. The very weakly coordinating anion with R=C(CF3)3 led to the salt Ag(P3N3Cl6)2+[A ...
Dimensionally Stable Anodes (DSA®) are electrodes composed of a metal support and an oxide coating (catalyst). Particularly in this thesis, the Ti/IrO2 electrode was used for the study of the fraction of the surface which participates effectively in the in ...
This work was accomplished in the context of systematic examination of a role played by electrolyte cation composition in electroreduction processes. The electrochemical behaviour of molten salts systems where CsCl was used as solvent for potassium and cae ...
A series of cationic metalla-rectangles of the general formula [(p-cymene)4Os4(OO.intrsec.OO)2(N.intrsec.N)2]4+ have been obtained in methanol from the dinuclear arene osmium precursors [(p-cymene)2Os2(OO.intrsec.OO)2Cl2] (OO.intrsec.OO = 2,5-dihydroxy-1,4 ...
The electropolymn. of Ru and Os bis-terpyridine complexes that form rodlike polymers with bithienyl, quaterthienyl, or hexathienyl bridges were studied. Absorption spectroscopy, SEM, and cyclic voltammetry were used to characterize the monomers and resulti ...
A new class of benzimidazole-substituted 8-hydroxyquinoline ligands has been prepared that contain a monoanionic tridentate N,N,O-coordinating unit. These ligands form charge-neutral lanthanide complexes of the type [Ln(LR) 3] · nH2O or [Ln2(L2)3] · nH2O ( ...
Titanium oxide (Ti(O)) xerogel films functionalized by protoporphyrin IX (PPIX) and ferrocene carboxylic acid (FCA) were deposited on indium tin oxide (ITO) electrodes following a sol–gel synthesis. PPIX and FCA were first complexed to titanium oxide precu ...
A mononuclear iron bis(carbonyl) pyridonate complex (1), which exhibits several common structural features with the active site of the iron−sulfur cluster-free [Fe]- hydrogenase, was synthesized and characterized. Spectroscopic data of 1 suggests a 2+ oxid ...
Reaction of 1,1'-bis(diphenylphosphino)binaphthol (BINAPO, 1) with [RuCl2(η6-arene)]2 in methanol leads to dinuclear BINAPO-bridged Ru compounds [{RuCl2(η6-p-cymene)}2-(μ-BINAPO)], 2a, in ne ...