Assembly of High-Spin [Fe-3] Clusters by Ligand-Based Multielectron Reduction
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A novel palladium-catalyzed domino spirocyclization for the formation of spiropyrrolidine-3,3'-oxindoles is reported. Both Heck and aminopalladation are viable pathways and the route that occurs depends on the ligand used and 2-(2-MeC6H4)C6H4P(CMe3)2 is re ...
Two monotopic tridentate ligands, namely HLAB1 and HLAB2 have been synthesized which feature an acridone chromophore fused on a benzimidazolepyridine framework. They differ from each other by their connection points between a N-methylacridone and a N-methy ...
A series of tridentate benz- ACHTUNGTRENUNGimidazole-substituted pyridine-2-carboxylic acids have been prepared with a halogen, methyl or alkoxy group in the 6-position of the benzimidazole ring, which additionally contains a solubilising N-alkyl chain. Th ...
Everybody form a circle: Careful design of ligand strands and their reaction with Cu2+ ions leads to the formation of the title helicates. Incorporation of differing numbers of N-donor units within a ligand strand containing a phenyl spacer results in a pe ...
An improved synthesis of 2-(2′-benzothiazole)- and 2-(2′-benzoxazole)-8-hydroxyquinoline ligands that combine a tridentate N,N,O-chelating unit for metal binding and extended chromophore for light harvesting is developed. The 2-(2′-benzoxazole)-8-hydroxyqu ...
Centrin, an EF-hand calcium-binding protein, has been shown to be involved in the duplication of centrosomes, and Sfi1 (Suppressor of fermentation-induced loss of stress resistance protein 1) is one of its centrosomal targets. There are three isoforms of h ...
This thesis encompasses work on the coordination chemistry and catalytic activity of half sandwich ruthenium(II)-arene phosphine complexes. The investigation of phosphine dissociation and association reactions of these complexes represents the unifying the ...
There are only few structural thermodynamic and kinetic studies on labile octahedral complexes available today. Octahedral paramagnetic compounds of cobalt(II) have an optimum electronic relaxation leading to NMR spectra with good resolution. Therefore, th ...
Microwave heating was employed to promote arene displacement in reactions of [{(p-cymene)RuCl2}(2)] or [{(1,3,5-C-6,H(3)iPr(3))RuCl2}(2)] with neutral chelate ligands L-L' [L-L': 1,1'-bis(diphenylphosphanyl)methane, 1,1'- bis(diphenylphosphanyl)ferrocene, ...
A series of europium(III) and terbium(III) complexes of three 1,4,7-triazacyclononane-based pyridine containing ligands were synthesized. The three ligands differ from each other in the substitution of the pyridine pendant arm, namely they have a carboxyli ...