Generation of hydroxyl radical during chlorination of hydroxyphenols and natural organic matter extracts
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This thesis is devoted to the study of oxygen reduction reaction catalysed by porphyrins at the interface between two immiscible electrolyte solutions (ITIES). Electrochemical and spectrophotometric techniques are introduced to these interfaces in order to ...
Synthetic boron-doped diamond thin film is a new promising anode material. Because of its properties (high anodic stability under drastic conditions and wide potential window), it is widely investigated for numerous possible electrochemical applications su ...
Tyrosine nitration, often observed during neurodegenerative disorders under nitrative stress, is usually considered to be induced chemically either by nitric oxide and oxygen forming nitrogen dioxide or by the decomposition of peroxynitrite. It can also be ...
Dissolved organic matter (DOM) has recently been shown to reduce the transformation rate of various aqueous organic contaminants submitted to oxidation by excited triplet states, apparently by inhibiting the transformation of oxidation intermediates. The m ...
In the present work, herbicide 2,4,5-trichlorophenoxyacetic acid, more commonly known as 2,4,5-T herbicide, has been completely mineralized (i.e. transformed into CO2 and H2O) in satd. aq. solns. using a semi-industrial electrochem. cell that contains a bo ...
Synthetic boron-doped diamond (BDD) thin film is an electrode material with high chemical and dimensional stability, low background current and a very wide potential window of water stability. Upon anodic polarization, BDD generates hydroxyl radicals that ...
The increase of bacterial resistance against various disinfection processes is a worrying phenomenon. As a consequence, the search for alternative techniques for fighting micro-organisms has become one of the major issues of these last few years. In this d ...
Diamond films with different levels of doping have been the subject of applications and fundamental research in electrochemistry, opening up a new branch known as the electrochemistry of diamond. The electrochemical properties of diamond mostly depend on t ...
The electrogeneration of hydroxyl radicals was studied at a synthetic B-doped diamond (BDD) thin film electrode. Spin trapping was used for detection of hydroxyl radicals with 5,5-dimethyl-1-pyrroline-N-oxide and with salicylic acid using ESR and liq. chro ...
The authors have studied the electrochem. oxidn. of H2SO4 on B-doped synthetic diamond electrodes (BDD) obtained by hot filament CVD on p-Si. High current efficiency for H2SO4 oxidn. to peroxodisulfuric acid can be achieved in concd. H2SO4 (>2M) at moderat ...