Chemical kineticsChemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is different from chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate. Chemical kinetics includes investigations of how experimental conditions influence the speed of a chemical reaction and yield information about the reaction's mechanism and transition states, as well as the construction of mathematical models that also can describe the characteristics of a chemical reaction.
Fundamental groupIn the mathematical field of algebraic topology, the fundamental group of a topological space is the group of the equivalence classes under homotopy of the loops contained in the space. It records information about the basic shape, or holes, of the topological space. The fundamental group is the first and simplest homotopy group. The fundamental group is a homotopy invariant—topological spaces that are homotopy equivalent (or the stronger case of homeomorphic) have isomorphic fundamental groups.
Fundamental groupoidIn algebraic topology, the fundamental groupoid is a certain topological invariant of a topological space. It can be viewed as an extension of the more widely-known fundamental group; as such, it captures information about the homotopy type of a topological space. In terms of , the fundamental groupoid is a certain functor from the category of topological spaces to the category of groupoids. Let X be a topological space. Consider the equivalence relation on continuous paths in X in which two continuous paths are equivalent if they are homotopic with fixed endpoints.
Ceramic metal-halide lampA ceramic metal-halide lamp (CMH), also generically known as a ceramic discharge metal-halide (CDM) lamp, is a type of metal-halide lamp that is 10–20% more efficient than the traditional quartz metal halide and produces a superior color rendition (80-96 CRI). Applications for these lamps include shop lighting, street lighting, architectural lighting and agricultural lighting including grow lights. A CMH light was first exhibited by the Thorn Lighting Group in 1981 at the Hannover World Light Fair, and the first commercial ceramic metal halide lamps were distributed by Philips in 1994.
Oxonium ionIn chemistry, an oxonium ion is any cation containing an oxygen atom that has three bonds and 1+ formal charge. The simplest oxonium ion is the hydronium ion (). Hydronium is one of a series of oxonium ions with the formula RnH3−nO+. Oxygen is usually pyramidal with an sp3 hybridization. Those with n = 1 are called primary oxonium ions, an example being protonated alcohol (e.g. methanol). In acidic media, the oxonium functional group produced by protonating an alcohol can be a leaving group in the E2 elimination reaction.
