Molecular Platform for Frequency Upconversion at the Single-Photon Level
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This thesis reports on results of three different experiments of photo-induced structural dynamics in the condensed phase, investigated by time-resolved pump-probe spectroscopy with femtosecond time-resolution. In the first part, we address the ultrafast d ...
Infrared spectroscopy using semiconductor lasers is a promising technique for trace gas detection. It allows a continuous and real time monitoring of several species, with a high sensitivity and a good selectivity. Among all the possible methods two are pa ...
The present work is devoted to the study of the dynamics of multi-photon processes in semiconductor heterostructures. A time-dependent description is important for understanding in detail the transient response of semiconductors excited by ultrashort optic ...
We develop a dynamical theory for the optical injection of charge and spin current originating from the interferences between two coherent laser pulses of frequencies omega and 2omega. Multiband Bloch equations which include one- and two-photon interband t ...
Vibrational sum-frequency generation (SFG) employing femtosecond infrared (IR) laser pulses is used to study the dynamics of the C-O stretch vibration on Ru(0 0 1). Time-resolved measurements of the free induction decay (FID) of the IR-polarization for 0.3 ...
Femtosecond pump pulses are strongly attenuated in lithium niobate owing to two-photon absorption; the relevant nonlinear coefficient beta(p) ranges from similar to 3.5 cm/GW for lambda(p) = 388 nm to similar to 0.1 cm/GW for 514 nm. In collinear pump-prob ...
Sensitive photoacoustic detection of methane (CH4), hydrogen chloride (HCI) and water vapour (H2O) in the near-infrared range using semiconductor DFB lasers is reported. A detection limit of 0.17 ppm of CH4, 0.2 ppm of HCI and 0.024 ppm of H2O (signal-to-n ...
A photoacoustic sensor has been developed for trace-gas monitoring using a near-infrared semiconductor laser emitting in the 2ν3 band of methane at 1.65 μm. The apparatus was designed for on-line process control in the manufacturing of the novel low-water- ...
A photoacoustic multi-gas sensor using tuneable laser diodes in the near-infrared region is reported. An optimized resonant configuration based on an acoustic longitudinal mode is described. Automatic tracking of the acoustic resonance frequency using a pi ...
Temperature dependences of the optic phonons in PbSc1/2Ta1/2O3 (PST) sol-gel films deposited on sapphire substrates were studied by means of Fourier transform far-infrared transmission spectroscopy in the temperature range of 20-900 K. Four films displayin ...