Electron paramagnetic resonanceElectron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spins excited are those of the electrons instead of the atomic nuclei. EPR spectroscopy is particularly useful for studying metal complexes and organic radicals. EPR was first observed in Kazan State University by Soviet physicist Yevgeny Zavoisky in 1944, and was developed independently at the same time by Brebis Bleaney at the University of Oxford.
Electron affinityThe electron affinity (Eea) of an atom or molecule is defined as the amount of energy released when an electron attaches to a neutral atom or molecule in the gaseous state to form an anion. X(g) + e− → X−(g) + energy This differs by sign from the energy change of electron capture ionization. The electron affinity is positive when energy is released on electron capture. In solid state physics, the electron affinity for a surface is defined somewhat differently (see below).
Neutrinoless double beta decayThe neutrinoless double beta decay (0νββ) is a commonly proposed and experimentally pursued theoretical radioactive decay process that would prove a Majorana nature of the neutrino particle. To this day, it has not been found. The discovery of the neutrinoless double beta decay could shed light on the absolute neutrino masses and on their mass hierarchy (Neutrino mass). It would mean the first ever signal of the violation of total lepton number conservation. A Majorana nature of neutrinos would confirm that the neutrino is its own antiparticle.
R-processIn nuclear astrophysics, the rapid neutron-capture process, also known as the r-process, is a set of nuclear reactions that is responsible for the creation of approximately half of the atomic nuclei heavier than iron, the "heavy elements", with the other half produced by the p-process and s-process. The r-process usually synthesizes the most neutron-rich stable isotopes of each heavy element. The r-process can typically synthesize the heaviest four isotopes of every heavy element, and the two heaviest isotopes, which are referred to as r-only nuclei, can be created via the r-process only.
S-processThe slow neutron-capture process, or s-process, is a series of reactions in nuclear astrophysics that occur in stars, particularly asymptotic giant branch stars. The s-process is responsible for the creation (nucleosynthesis) of approximately half the atomic nuclei heavier than iron. In the s-process, a seed nucleus undergoes neutron capture to form an isotope with one higher atomic mass. If the new isotope is stable, a series of increases in mass can occur, but if it is unstable, then beta decay will occur, producing an element of the next higher atomic number.
Ionization energyIn physics and chemistry, ionization energy (IE) (American English spelling), ionisation energy (British English spelling) is the minimum energy required to remove the most loosely bound electron of an isolated gaseous atom, positive ion, or molecule. The first ionization energy is quantitatively expressed as X(g) + energy ⟶ X+(g) + e− where X is any atom or molecule, X+ is the resultant ion when the original atom was stripped of a single electron, and e− is the removed electron.
Electron captureElectron capture (K-electron capture, also K-capture, or L-electron capture, L-capture) is a process in which the proton-rich nucleus of an electrically neutral atom absorbs an inner atomic electron, usually from the K or L electron shells. This process thereby changes a nuclear proton to a neutron and simultaneously causes the emission of an electron neutrino. Proton + Electron → Neutron + Electron Neutrino or when written as a nuclear reaction equation, ^{0}{-1}e + ^{1}{1}p -> ^{1}{0}n + ^{0}{0} ν Since this single emitted neutrino carries the entire decay energy, it has this single characteristic energy.
X-ray detectorX-ray detectors are devices used to measure the flux, spatial distribution, spectrum, and/or other properties of X-rays. Detectors can be divided into two major categories: imaging detectors (such as photographic plates and X-ray film (photographic film), now mostly replaced by various digitizing devices like s or flat panel detectors) and dose measurement devices (such as ionization chambers, Geiger counters, and dosimeters used to measure the local radiation exposure, dose, and/or dose rate, for example, for verifying that radiation protection equipment and procedures are effective on an ongoing basis).
Ab initioAb initio (ˌæb_ᵻˈnɪʃioʊ ) is a Latin term meaning "from the beginning" and is derived from the Latin ab ("from") + initio, ablative singular of initium ("beginning"). Circa 1600, from Latin, literally "from the beginning", from ablative case of initium "entrance", "beginning", related to verb inire "to go into", "enter upon", "begin". Ab initio (abbreviation: ab init.) is used in several contexts, including the following: In law, ab initio refers to something being the case from the start or from the instant of the act rather than from when the court declared it so.
Ab initio quantum chemistry methodsAb initio quantum chemistry methods are computational chemistry methods based on quantum chemistry. The term ab initio was first used in quantum chemistry by Robert Parr and coworkers, including David Craig in a semiempirical study on the excited states of benzene. The background is described by Parr. Ab initio means "from first principles" or "from the beginning", implying that the only inputs into an ab initio calculation are physical constants.
