Reaction and Flow Variants/Invariants in Chemical Reaction Systems with Inlet and Outlet Streams
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In recent years, chemometric methods for the analysis of multivariate kinetic data have considerably progressed. Kinetic hard-modelling is one of these methods that is based on the rate law and used to determine the kinetic parameters (e.g. rate constants) ...
Accelerated bleaching, photobleaching and mineralization of the non-biodegradable azo-dye, Orange II, was obsd. with oxone in solns. with Co2+-ions. The bleaching rate of Orange II in the dark was found to follow a first-order kinetics with respect to [Co2 ...
The goal of our project (HES-SO n°11246) is to develop chemometric methods that enhance the development of chemical reactions. Semi-batch experiments are performed using a fully automated chemical reactor. Real-time analytical data, infrared (IR) spectra f ...
Anterior-posterior polarity in the Caenorhabditis elegans zygote depends on two groups of PAR proteins, as well as on cortical flow. Recent work now demonstrates that this polarization results from a transition in a bistable reaction-diffusion system of PA ...
Monitoring, control and optimization of chemical reaction systems often requires in-depth analysis of the underlying reaction mechanisms. This dissertation investigates appropriate tools that facilitate the analysis of homogeneous and gas-liquid reaction s ...
The bifunctional catalyst 6'-deoxy-6'-acylamino-beta -isocupreidine served both as a base to trigger the in situ generation of N-sulfonylimine from readily available alpha -amidosulfones and as a chiral nucleophile to initiate the enantioselective aza-Mori ...
The influence of IrO2 loading on the effectiveness factor Et of the electrochemical oxidation of isopropanol was investigated A model has been proposed based on three main reactions electrochemical IrO2 oxidation to IrO3 chemical oxidation of the organic c ...
The occurrence of alkali-silica and alkali-silicate reactions causes damage in concrete. Even though the reaction has been known for some time, the progress of reaction in affected structures is difficult to predict. This research programme aims to study t ...
A new algorithm, called boosted hybrid method, is proposed for the simulation of chemical reaction systems with scale-separation in time and disparity in species population. For such stiff systems, the algorithm can automatically identify scale-separation ...
Chemiluminescence, i.e. the emission of light from a chemical reaction, offers interesting opportunities for developing point-of-care biosensors. However, commercially available systems are expensive, bulky, and primarily addressed to laboratory usage. The ...