Publication

Decreasing the Stability of Borohydride with Ionic Liquids for Hydrogen Storage and Carbon Dioxide Conversion

Related publications (168)

Influence of the Interaction between Hydrogen Sulfide and Ionic Liquids on Solubility: Experimental and Theoretical Investigation

Paul Joseph Dyson, Gabor Laurenczy, Ana Vidis, Cinzia Chiappe

The soly. of H2S in a series of 1-butyl-3-methylimidazolium ([bmim]+) based ionic liqs. (ILs) with different anions, chloride, tetrafluoroborate ([BF4]-), hexafluorophosphate ([PF6]-), triflate ([TfO]-), and bis(trifluoromethyl)sulfonylimide ([Tf2N]-), and ...

2007

Structure of nitrile-functionalized alkyltrifluoroborate salts

Paul Joseph Dyson, Zhaofu Fei, Dongbin Zhao

Two nitrile-functionalized alkyltriflouroborate anion based complexes [(Ph3P)(2)N][CH3CH(BF3)CH2CN] and [K(18-crown-6)][CH3CH(BF3)CH2CN] were synthesized and characterized by spectroscopic methods and single X-ray diffraction analysis. In the former comple ...

2005

Synthesis and characterization of ionic liquids incorporating the nitrile functionality

Paul Joseph Dyson, Zhaofu Fei, Dongbin Zhao

A series of imidazolium salts with the nitrile functional group attached to the alkyl side chain, viz. [C(n)CNmim][X] (where C(n)CNmim is the 1-alkylnitrile-3-methylimidazolium cation and C-n = (CH2)(n), n = 1-4; X = Cl, PF6, and BF4) and [C(3)CNdmim][X] ( ...

2004

Carbon dioxide reduction in biphasic aqueous-ionic liquid systems by pressurized hydrogen

Gabor Laurenczy

This work reports the hydrogenation of carbon dioxide/inorganic carbonate salts to formic acid/formate in two phase systems comprising an ionic phase, in which the catalyst is immobilized, and an aqueous phase in which the carbonates and formate are confin ...

2003

The organometallic approach to molecular diversity - halogens as helpers

A review. Strategies to functionalize simple, though structurally challenging, compds. in regiodivergent manner are outlined. The starting materials are inexpensive (5-500 e/mol) arenes or heterocycles bearing heterosubstituents such as Cl, F, CF3, OCF3, a ...

2001

Reversible Gelation of Poly(dimethylsiloxane) with Ionic and Hydrogen-Bonding Substituents

Harm-Anton Klok

Poly(dimethylsiloxane) copolymers containing a small fraction of carboxylic acid or Zn-carboxylate groups were prepared and compared regarding reversible gelation by hydrogen-bonding and ion-pair interaction. The polymers were synthesized by condensation o ...

1999

Optional Site Selectivity in the Metalation of o- and p-Anisidine through Matching of Reagents with Neighboring Groups

N-Protected o- and p-anisidines (2- and 4-methoxyanilines) undergo a hydrogen/metal exchange at the position adjacent to either the oxygen or nitrogen atom depending on what organometallic base is employed. These synthetically useful findings support previ ...

1996

Light-induced charge separation and water cleavage in microheterogenous aqueous systems

Michael Graetzel

This paper is concerned with reaction systems in which fuel production is achieved by illumination of aqueous solutions. Research interest in this field focuses on the photoredox reaction A + D [graphic omitted] A–+ D+ in which A and D are solutes of which ...

1981

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