Strong coloration of nanoporous tungsten oxides by in-vacuo lithiation for all-solid-state electrochromic devices
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The anodic behavior of Ni in HF-HCl aq. solns. was examd. The current efficiency for Ni dissoln. was detd. from the wt. loss of Ni polarized anodically, assuming that Ni dissolves as Ni2+. The dissoln. rate decreases markedly for a HF concn. of .apprx.50%. ...
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Forward biasing of transparent nanocryst. TiO2 (anatase) films in lithium ion-contg. org. electrolytes leads to rapid and reversible coloration due to electron accumulation and Li+ intercalation in the anatase lattice. Absorption of >90% light throughout t ...
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Electrochem. insertion of lithium in nanoporous and CVD samples of anatase was studied by chronoamperometry. The currents following cathodic and anodic potential steps were monitored as a function of film thickness, temp., and electrolyte concn. The time d ...
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Intercalation of lithium ions in nanoporous anatase TiO2 was studied with XPS using a novel electrochem. prepn. technique. The electrolyte was 0.5 M LiClO4 in acetonitrile (not water-free). The electrochem. insertion of lithium ions creates reduced Ti ions ...
Forward biasing of transparent nanocryst. TiO2 (anatase) films in Li ion contg. org. electrolytes leads to rapid and reversible coloration due to electron accumulation and Li+ intercalation in the anatase lattice. Absorption of > 90% light throughout the v ...
The reaction of FePS3 single crystals with a 1.6M n-butyl lithium solution in n-hexane has been followed through de electrical conductivity measurements as a function of the intercalation time. In order to investigate the influence of lithium insertion on ...