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Intermolecular Pd(0)-Catalyzed Atropo-enantioselective C-H Arylation of Heteroarenes and Other Investigations into the Enantioselective Activation of Challenging C(sp3)-H Bonds

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The main objectives of this work are 2-fold : The development of a novel type of composite material based on carbon nanofibers supported on sintered metal fibers filters (CNF/SMF) and to explore the use of this material as a catalytic support for a model r ...

EPFL2006

The importance of catalysis in chemistry has not to be proved anymore. Be it homogeneous or heterogeneous catalysis, the constant progresses observed in that field proves its obvious interest. The asymmetric homogeneous catalysis is a method of choice to s ...

EPFL2005

The principal objective of this thesis is the development of a palladium catalyst supported on woven fabrics of activated carbon fibers (ACF) for the reactions of hydrogenations in liquid phase and the design of multiphase reactors using the characteristic ...

EPFL2005

Low Temperature Decomposition of Nitrous Oxide over Fe/ZSM-5: Modelling of the Dynamic Behaviour

Albert Renken, Lioubov Kiwi

The kinetics of N2O decomposition to gaseous nitrogen and oxygen over HZSM-5 catalysts with low content of iron (

2005

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Carbonate radical (CO3-) is a powerful oxidant that is present in sunlit surface waters and in waters treated by advanced oxidation processes. The production of CO3- in aqueous solution through oxidation of carbonate anion by excited triplet states of arom ...

2005

Catalytic hydroformylation of olefins has been carried out in a HP FT-IR cell using RhH(CO)(PPh3)(3) catalytic precursor. A different behaviour was noticed between a terminal (hex-1-ene) and an internal alkene (cyclohexene) and different rate-determining s ...

2004

We have investigated different possible mechanisms for the cis-trans isomerization in triply bonded ditungsten complexes with stoichiometry W2Cl4(NHEt)2(PMe3)2 using static d. functional calcns. as well as Car-Parrinello simulations. Our studies reveal an ...

2001

This thesis deals with a laboratory study of heterogeneous reactions involving bromine and chlorine containing reservoir species on alkali salt substrates which are relevant to the marine boundary layer, and on ice substrates which are relevant to the lowe ...

EPFL2001

Microgravimetric determination of polycondensation kinetics

Albert Renken

The polycondensation of bis(ethylene glycol) terephthalate to poly(ethylene terephthalate) was investigated by thermogravimetric measurements at 260-300 Deg. A model is developed which enables to ext. the apparent kinetic parameters from the measured mass ...

Wiley-VCH1998

The electrochem. promotion of RuO2 catalyst films, deposed onto yttria stabilized zirconia solid electrolyte (YSZ), was studied for the gas phase combustion of ethylene. Two order of magnitude increase in the reaction rate was obtained during anodic polari ...

1998