Grafting of Alkali Metals on Fumed Silica for the Catalytic Dehydrogenation of Methanol to Formaldehyde
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This paper investigates the effect of KOH and NaOH on C-S-H structure and solubility. Both KOH and NaOH have a similar effect, they increase pH values and silicon concentrations, and decrease calcium concentrations. At higher alkali hydroxide concentration ...
PERGAMON-ELSEVIER SCIENCE LTD2022
For several decades, food-grade synthetic amorphous silica (SAS) have been used as a technological additive to reduce caking of food powders. Human exposure is thus inevitable and safety concerns are taken seriously. The toxicity of silica in general and S ...
PERGAMON-ELSEVIER SCIENCE LTD2020
The alkali-silica reaction (ASR), also known as concrete cancer, is one of the most prevalent causes of concrete degradation. In this chemical reaction, amorphous silica in the aggregates reacts with alkalis in the pore solution. By absorbing water, hydrop ...
EPFL2022
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The dissolution kinetics of silica-containing minerals in aggregates influences strongly the process of ASR in concrete. In this paper, the effect of different ions on the dissolution rates of SiO2 (amorphous and quartz) and feldspars at high pH values was ...
PERGAMON-ELSEVIER SCIENCE LTD2022
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Oxide inclusions are ubiquitous in steel and are known to affect, generally in a negative sense, the mechanical performance of steel products. Micromechanical properties of those phases are therefore important, yet they have remained largely unexplored. We ...
2022
The occurrence of cracking due to alkali silica reaction (ASR) affects the service life of concrete structures. The dissolution of silica-containing minerals within aggregates causes the formation of ASR products, which fill macroscopic cracks and cause th ...
EPFL2021
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Alkali-silica reaction (ASR) is a concrete disease that leads to its degradation. ASR is the reaction between the amorphous silica (SiO2 ) and the alkali ions (Na + , K + ), leading to expansion of concrete in presence of Ca 2+ . In this study, it is assum ...
2020
Calcium silicate hydrate (C-S-H) is the main hydration product in Portland and blended cements, and greatly affects durability and mechanical properties of the hydrated cement. In the presence of Al-rich supplementary cementitious materials (SCMs), C-(A-)S ...
EPFL2022
Our society is engaged in a major shift towards more sustainable industries. The required transition from fossils to renewable resources with low greenhouse gas emission is specifically challenging in the transportation sector where high thermal efficiency ...
EPFL2020
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Materials with thermal-invariant elastic properties are of interest for resonant device frequency and dimensional stability of precision devices. Here, we demonstrate that the temperature coefficient of elasticity (TCE) of amorphous silica can be locally r ...
