Elemental and Thermo-gravimetric Characterization of Trace Metals in Leaves and Soils as Bioindicators of Pollution in Kyiv City

In this study, leaf and soil samples were used as bio-monitors for different alkali and heavy metals at six different locations in Kyiv city. Using x–y plots of the inductively coupled plasma optical emission spectroscopy (ICP-OES) data measured the discrepancy level in elemental composition between the different investigated areas; the correlation between the concentrations in tree leaves and the samples from the surrounding soils were investigated. While the concentration of essential mineral elements and metals was found to be similar in several leaf and soil samples, in other samples, their concentration spread up to more than one order of magnitude. The concentration of metals was found to be higher in soil samples than in leaves. Thermo-gravimetric analysis (TGA) data helped to further characterize both types of samples. The metal removal during the incineration of the leaves was investigated by coupling a thermo-gravimetric analyzer to an inductively coupled plasma optical emission spectrometer (TGA-ICP-OES). The release of Cd, K, Na, Pb, and Zn during incineration at temperatures up to 960 °C was online monitored, and some insights were drawn about the behavior of such metals and the chemistry involved in the volatilization process.