Publication

Synthesizing the impacts of baseflow contribution on concentration-discharge (C-Q) relationships across Australia using a Bayesian hierarchical model

Abstract

Understanding concentration-discharge (C - Q) relationships can inform catchment solute and particulate export processes. Previous studies have shown that the extent to which baseflow contributes to streamflow can affect C-Q relationships in some catchments. However, the current understanding on the effects of baseflow contribution in shaping the C-Q patterns is largely derived from temperate catchments. As such, we still lack quantitative understanding of these effects across a wide range of climates (e.g. arid, tropical and subtropical). The study aims to assess how baseflow contributions, as defined by the median and the range of daily baseflow indices within individual catchments (BFI_m and BEI_range, respectively), influence C-Q slopes across 157 catchments in Australia spanning five climate zones. This study focuses on six water quality variables: electrical conductivity (EC), total phosphorus (TP), soluble reactive phosphorus (SRP), total suspended solids (TSS), the sum of nitrate and nitrite (NO,) and total nitrogen (TN). The impact of baseflow contributions is explored with a novel Bayesian hierarchical model. For sediments and nutrient species (TSS, NOx, TN and TP), we generally see largely positive C-Q slopes, which suggest a dominance of mobilization export patterns. Further, for TSS, NOx and TP we see stronger mobilization (steeper positive C-Q slopes) in catchments with higher values in both the BEI_m and BFI range, as these two metrics are positively correlated for most catchments. The enhanced mobilization in catchments with higher BEI_m or BEI_range is likely due to the more variable flow pathways that occur in catchments with higher baseflow contributions. These variable flow pathways can lead to higher concentration gradients between low flows and high flows, where the former is generally dominated by groundwater/slow subsurface flow while the latter by surface water sources, respectively. This result highlights the crucial role of flow pathways in determining catchment exports of solutes and particulates. Our study also demonstrates the need for further studies on how the temporal variations of flow regimes and baseflow contributions influence flow pathways and the potential impacts of these flow pathways on catchment C-Q relationships.

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Related concepts (37)
Baseflow
Baseflow (also called drought flow, groundwater recession flow, low flow, low-water flow, low-water discharge and sustained or fair-weather runoff) is the portion of the streamflow that is sustained between precipitation events, fed to streams by delayed pathways. It should not be confused with groundwater flow. Fair weather flow is also called base flow. Baseflow is important for sustaining human centers of population and ecosystems. This is especially true for watersheds that do not rely on snowmelt.
Surface runoff
Surface runoff (also known as overland flow or terrestrial runoff) is the unconfined flow of water over the ground surface, in contrast to channel runoff (or stream flow). It occurs when excess rainwater, stormwater, meltwater, or other sources, can no longer sufficiently rapidly infiltrate in the soil. This can occur when the soil is saturated by water to its full capacity, and the rain arrives more quickly than the soil can absorb it. Surface runoff often occurs because impervious areas (such as roofs and pavement) do not allow water to soak into the ground.
Streamflow
Streamflow, or channel runoff, is the flow of water in streams and other channels, and is a major element of the water cycle. It is one runoff component, the movement of water from the land to waterbodies, the other component being surface runoff. Water flowing in channels comes from surface runoff from adjacent hillslopes, from groundwater flow out of the ground, and from water discharged from pipes. The discharge of water flowing in a channel is measured using stream gauges or can be estimated by the Manning equation.
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