Hydro-processing of biomass using novel metal-organic framework (MOF)/polymer composite catalysts
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The reaction of hydrated lanthanide hexafluoroacetylacetonates, [Ln(hfa)(3)(H2O)(2)], with 1,4-disubstituted benzenes afforded a new series of one-dimensional coordination polymers Ln(hfa)(3)(Q), where Ln = Eu, Gd, Tb, and Lu and Q = 1,4-diacet ...
With increasing emphasis placed on cleaner chemical synthesis, energy efficiency and waste minimisation, the manufacture of pharmaceuticals and fine chemicals is undergoing a progressive shift from conventional stoichiometric organic processes to a harness ...
The main obstacles in the widespread use of hydrogen as energetic alternative to fossil fuels are storage problems intrinsically linked to its extremely light and explosive nature. Since no ideal storage systems currently exist, reversible fixation of hydr ...
We report for the first time 99.9% yield of aminocompounds and high TOFs (up to 61 s(-1)) in the liquid-phase hydrogenation of several para-substituted (-OH, -OCH3, -CH3, -H, -Br, -Cl, -COOH and -NO2) nitroaromatics over quasi-monodispersed (ca. 3.3 nm fro ...
With a span as long as the history of polymer science itself, post-polymerization modification represents a versatile platform for the preparation of diversely functionalized polymers from a single precursor. Starting with the initial efforts by Staudinger ...
Rh NPs coated with a PVP-derived polymer, that combines several distinct protective interactions, exhibit superior thermal and catalytic stability compared to analogue NPs coated with PVP. ...
In recent years, a strong emphasis in research towards creating sustainable and environmental friendly chemical processes has propelled the development of novel types of catalytic systems that combine advantages from homogeneous and heterogeneous processes ...
A ruthenium meso-tetra[4-(vinylbenzoxy)benzyl]porphyrin catalyst with four meso-polymerizable side chains was synthesized in three steps from commercially available starting materials. The polymerizable side chains allowed the incorporation of this complex ...
Valorization of lignocellulosic biomass for the production of commodity chemicals using various chemical methods continues to attract considerable attention. A wide and diverse range of different chemicals can be obtained from biomass and many different do ...
Supported metal catalysts are important from both an industrial and a scientific point of view. They are used, amongst others, in large-scale processes such as catalytic reforming, hydrotreating, polymerization reactions and hydrogenations. Often, these ca ...