Galvanic replacement reactions of Ga and In with Cu for the synthesis of bimetallic nanoparticles
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Nowadays the development of stable and highly efficient Solid-Contact Ion-Selective Electrodes (SC-ISEs) attracts much attention in the research community because of the great expansion of portable analytical devices. In this work, we present highly stable ...
Proton exchange membrane water electrolysis (PEMWE) is a promising technology for electricity-to-fuel conversion which allows for direct production of hydrogen from water. One of the key problems limiting widespread implementation of PEMWE into energy syst ...
The mechanical strength of metals depends on their resistance against various microscopic
deformation processes. In ductile metals, the most important process is shearing of the crystal
lattice by dislocations. One of the fundamental aspects of dislocation ...
Soluble transition metals in particulate matter (PM) can generate reactive oxygen species in vivo by redox cycling, leading to oxidative stress and adverse health effects. Most metals, such as those from roadway traffic, are emitted in an insoluble form, b ...
Recent data on the Noble metal (Pd-Pt-Rh-Ir-Au-Ag-Cu-Ni) high entropy alloys (HEAs) shows some of these materials to have impressive mechanical properties. Here, a mechanistic theory for the temperature-, composition-, and strain-rate-dependence of the ini ...
Global production rates of metals vary from iron at 1.4 billion ton per year to platinum with 200 ton per year. Resource scarcity starts to manifest itself in rising prices and supply limitations, and metal substitution has been a major argument among econ ...
The industrial production of aromatic amines, essential intermediates for the synthesis of several drugs, dyes, pigments and agrochemicals, requires the use of heterogeneous catalysis. These molecules were formerly produced by the Béchamp reduction, a non- ...
The total resources form copper, zinc and lead was estimated from a reworking of the literature. The data was used as input to the integrated systems dynamics model BRONZE, and used to estimate the global supply of these metals and the by-products antimony ...
The critical rates of extraction of some metals was explored using a methodology based on the thinking behind critical loads for sulphur and nitrogen deposition developed in Europe 1990- 2010. With a long-term sustainability view in mind, critical rates ba ...
The aim of the present thesis is the development of a new Pt-based bulk metallic glass based on the ternary system of Pt-B-Si that i) complies with the hallmarking standard Pt 850 (i.e. with at least 85 wt.-pct of Pt); ii) provides high hardness (HV>600) a ...