Spin trappingSpin trapping is an analytical technique employed in chemistry and biology for the detection and identification of short-lived free radicals through the use of electron paramagnetic resonance (EPR) spectroscopy. EPR spectroscopy detects paramagnetic species such as the unpaired electrons of free radicals. However, when the half-life of radicals is too short to detect with EPR, compounds known as spin traps are used to react covalently with the radical products and form more stable adduct that will also have paramagnetic resonance spectra detectable by EPR spectroscopy.
Reaction mechanismIn chemistry, a reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs. A chemical mechanism is a theoretical conjecture that tries to describe in detail what takes place at each stage of an overall chemical reaction. The detailed steps of a reaction are not observable in most cases. The conjectured mechanism is chosen because it is thermodynamically feasible and has experimental support in isolated intermediates (see next section) or other quantitative and qualitative characteristics of the reaction.
American Civil WarThe American Civil War (April 12, 1861 – May 26, 1865; also known by other names) was a civil war in the United States. It was fought between the Union ("the North") and the Confederacy ("the South"), the latter formed by states that had seceded. The central cause of the war was the dispute over whether slavery would be permitted to expand into the western territories, leading to more slave states, or be prevented from doing so, which many believed would place slavery on a course of ultimate extinction.
Origins of the American Civil WarHistorians who address the origins of the American Civil War today agree that the preservation of the institution of slavery was the principal aim of the 11 Southern states (seven states before the onset of the war and four states after the onset) that declared their secession from the United States (the Union) and united to form the Confederate States of America (known as the "Confederacy").
Radical RepublicansThe Radical Republicans (later also known as "Stalwarts") were a faction within the Republican Party originating from the party's founding in 1854—some six years before the Civil War—until the Compromise of 1877, which effectively ended Reconstruction. They called themselves "Radicals" because of their goal of immediate, complete, and permanent eradication of slavery in the United States. They were opposed during the war by the Moderate Republicans (led by President Abraham Lincoln), and by the Democratic Party.
Abraham LincolnAbraham Lincoln (ˈlɪŋkən ; February 12, 1809 – April 15, 1865) was an American lawyer, politician, and statesman who served as the 16th president of the United States from 1861 until his assassination in 1865. Lincoln led the Union through the American Civil War to defend the nation as a constitutional union and succeeded in abolishing slavery, bolstering the federal government, and modernizing the U.S. economy. Lincoln was born into poverty in a log cabin in Kentucky and was raised on the frontier, primarily in Indiana.
Complementation (genetics)Complementation refers to a genetic process when two strains of an organism with different homozygous recessive mutations that produce the same mutant phenotype (for example, a change in wing structure in flies) have offspring that express the wild-type phenotype when mated or crossed. Complementation will ordinarily occur if the mutations are in different genes (intergenic complementation). Complementation may also occur if the two mutations are at different sites within the same gene (intragenic complementation), but this effect is usually weaker than that of intergenic complementation.
