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Bulk homochirality of a 3-D inorganic framework: ligand control of inorganic network chirality

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Philip Pattison
2009

Abstract

Enantioselective synthesis of a 3-D inorganic net has been achieved leading to metal–organic frameworks built from cobalt-oxide helices in which handedness is controlled by the chirality of the linked ligand.

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https://infoscience.epfl.ch/entities/publication/2ba3a8cf-a71d-4f5c-93ef-9f3038a7ca33

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Related concepts (11)

Metal–organic framework

Metal–organic frameworks (MOFs) are a class of compounds consisting of metal clusters (also known as SBUs) coordinated to organic ligands to form one-, two-, or three-dimensional structures. The organic ligands included are sometimes referred to as "struts" or "linkers", one example being 1,4-benzenedicarboxylic acid (BDC). More formally, a metal–organic framework is an organic-inorganic porous extended structure. An extended structure is a structure whose sub-units occur in a constant ratio and are arranged in a repeating pattern.

Covalent organic framework

Covalent organic frameworks (COFs) are a class of materials that form two- or three-dimensional structures through reactions between organic precursors resulting in strong, covalent bonds to afford porous, stable, and crystalline materials. COFs emerged as a field from the overarching domain of organic materials as researchers optimized both synthetic control and precursor selection.

Coordination polymer

A coordination polymer is an inorganic or organometallic polymer structure containing metal cation centers linked by ligands. More formally a coordination polymer is a coordination compound with repeating coordination entities extending in 1, 2, or 3 dimensions. It can also be described as a polymer whose repeat units are coordination complexes.

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