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Asymmetric synthesis of enantioenriched zigzag-type molecular belts featuring copper/H8-binaphthol-catalyzed kinetic resolution of a resorcinarene derivative and subsequent transformations was developed. The acquired rigid and C4-symmetric belt exhibited remarkably enhanced photophysical and chiroptical properties in comparison to its conformationally fluxional macrocyclic precursor.
Qian Wang, Jieping Zhu, Hua Wu, Rémi Julien Sylvain Andres
Jérôme Waser, Bastian Antoine Rodolphe Claude Muriel, Vincent Géry C Pirenne