Convection–diffusion equationThe convection–diffusion equation is a combination of the diffusion and convection (advection) equations, and describes physical phenomena where particles, energy, or other physical quantities are transferred inside a physical system due to two processes: diffusion and convection. Depending on context, the same equation can be called the advection–diffusion equation, drift–diffusion equation, or (generic) scalar transport equation.
Atomic diffusionIn chemical physics, atomic diffusion is a diffusion process whereby the random, thermally-activated movement of atoms in a solid results in the net transport of atoms. For example, helium atoms inside a balloon can diffuse through the wall of the balloon and escape, resulting in the balloon slowly deflating. Other air molecules (e.g. oxygen, nitrogen) have lower mobilities and thus diffuse more slowly through the balloon wall.
Knudsen diffusionIn physics, Knudsen diffusion, named after Martin Knudsen, is a means of diffusion that occurs when the scale length of a system is comparable to or smaller than the mean free path of the particles involved. An example of this is in a long pore with a narrow diameter (2–50 nm) because molecules frequently collide with the pore wall. As another example, consider the diffusion of gas molecules through very small capillary pores.
Gauss's principle of least constraintThe principle of least constraint is one variational formulation of classical mechanics enunciated by Carl Friedrich Gauss in 1829, equivalent to all other formulations of analytical mechanics. Intuitively, it says that the acceleration of a constrained physical system will be as similar as possible to that of the corresponding unconstrained system. The principle of least constraint is a least squares principle stating that the true accelerations of a mechanical system of masses is the minimum of the quantity where the jth particle has mass , position vector , and applied non-constraint force acting on the mass.
