Monoglyme forms a mol. 1:1 adduct with AlBr3 which dissocs. into the ions AlBr2(DME)2+ and AlBr4- in DME, CH2Br2, and CDCl3 as solvents. A hexacoordinated Al center is present in the solid adduct AlBr3.diglyme. The O and Br atoms are arranged in a meridion ...
1996