Heterogeneous catalysis via light-heat dual activation: A path to the breakthrough in C1 chemistry
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This thesis deals with the combined utilisation of a reaction calorimeter, the RC1® commercialised by Mettler Toledo and equipped with a 2 L glass reactor, and the heat transfer dynamics modelling of industrial reactors. By doing so, the temperature evolut ...
The use of zeolites for catalytic reactions is a field in continuous development. Since it was demonstrated that metal-zeolites are efficient catalysts for NOx abatement, decomposition of nitrous oxide (N2O) over Fe-containing zeolites has attracted great ...
A novel microreactor with structured catalytic wall (SCWMR) has been developed for highly exothermic, gas/solid reactions and tested for the selective acetylene hydrogenation. The reactor design is similar to the so-called "slit microreactor". The structur ...
The possibility to increase the performance (productivity or selectivity) of a chemical reactor by using periodic variations of reaction parameters (e.g. reactant concentration or temperature) has been theoretically envisaged since the beginning of the 70t ...
Nitrogen-doped and un-doped carbon nanofibers layers, denoted as N-CNFs and CNFs respectively, coating the walls of cordierite monoliths have been used as support for Pd and Ru catalyst. They have been tested in bromate reduction in batch and continuous op ...
N2O decomposition to gaseous N-2 and O-2 catalyzed by a commercial Fe-ZSM-5 has been studied by different transient techniques: (i) via the transient response methods at ambient pressure, (ii) via the temporal analysis of products (TAP) reactor under vacuu ...
The objective of this thesis is the development of a compact reactor for continuous three-phase reactions in single-pass configurations. The design is based on a bubble column reactor staged with layers of catalytic material. To make the reactor suitable f ...
Two types of stainless steel microstructured reactors for catalytic gas-phase reactions have been developed and characterized with respect to their thermal behaviour under non-stationary temperature conditions. One of the reactors used (FTC-I) allowed peri ...
Catalytic gas-phase abatement of air containing 250 ppm of isopropanol (IPA) was carried out with a novel dielectric barrier discharge (DBD) reactor with the inner catalytic electrode made of sintered metal fibers (SMF). The optimization of the reactor per ...
This study addresses the development of a compact reactor for oxidative steam-reforming of methanol (OSRM) to produce hydrogen in autothermal mode for fuel cells. The string reactor uses catalytically active brass wires with a diameter of 500 mu m placed i ...