Publications related to Heterogeneous kinetics of some atmospherically relevant reactions

The Real Carbon K-edge

For many years, electron energy-loss (EEL) spectroscopy has been used to analyse the near-edge structure of the carbon ionization K-edge. Amorphous carbon has perhaps one of the most well known carbon ionization edges, with the spectrum featuring a large, ...

Cambridge University Press2008

Evaluated kinetic and photochemical data for atmospheric chemistry: Volume IV - gas phase reactions of organic halogen species

Michel Rossi

This article, the fourth in the series, presents kinetic and photochemical data sheets evaluated by the IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry. It covers the gas phase and photochemical reactions of organic halogen spec ...

2008

Nitrous Oxide Decomposition on the Binuclear $\left$ Center in Fe-ZSM-5 Zeolite

The reaction mechanism for nitrous oxide (

{N}_{2}O

) direct decomposition into molecular nitrogen and oxygen was studied on binuclear iron sites in Fe-ZSM-5 zeolite using the density functional theory (DFT). Starting from the hydroxylated bi-iron complex ...

2008

Sorption of hydrophobic organic compounds (HOC) in rapeseed oil bodies

Ian William Marison, Julien Boucher

Oil-bodies are minute plant organelles (0.5-2.0 mu m diameter) consisting of an oil core surrounded by a phospholipid monolayer/proteinaceous membrane. Oil-bodies have been isolated from rapeseed seeds and demonstrated to constitute a novel type of micro-c ...

2008

Study of gaseous interactions in carbon nanotube field-effect transistors through selective Si(3)N(4) passivation

Nicola Marzari

Carbon nanotube field-effect transistors with Si(3)N(4) passivated source and drain contacts and exposed carbon nanotube channel show n-type characteristics in air. In contrast, by passivating only the source contact, a diode-like behavior with a maximum c ...

2008

Formulation reproducing the ignition delays simulated by a detailed mechanism: Application to n-heptane combustion

This article is part of the project to model the kinetics of high-temperature combustions, occurring behind shock waves and in detonation waves. The "conventional" semi-empirical correlations of ignition delays have been reformulated, by keeping the Arrhen ...

2008

Quantum calculations on the acid catalyzed rearrangements of norborn-5-en-2-one, 7-oxanorborn-5-en-2-one and 7-azanorborn-5-en-2-one - The electron-releasing effect of homoconjugated carbonyl group

Pierre Vogel, Samuele Giani

Protonation of norbom-5-en-2-one gives 6-oxo-2-norbomyl cation (2) as most stable C7H9O+ cation. Quantum calculations at B3LYP/6-31G(d) level (gas phase, 1 atm, 25 degrees C) predict a C-s-structure for 2 that can be represented as an intramolecular pi-com ...

2008

Molecular relaxation effects in hydrogen chloride photoacoustic detection

Luc Thévenaz, Jean-Philippe Besson

A photoacoustic (PA) sensor has been developed to monitor hydrogen chloride at sub-ppm level in the 1740-nm region. The system was designed to control the process in the novel low-water-peak optical fiber manufacturing process. Relaxation effects in hydrog ...

Springer Verlag2008

Immobilization of rapeseed press-cake in an alginate matrix for the sorption of atrazine

Urs von Stockar, Ian William Marison, Véronique Breguet, Julien Boucher

Due to residual oil retained within it, rapeseed press-cake has been shown to be effective for the removal of atrazine from water through an absorption mechanism. However, it is difficult to put this into practice due to the hygroscopic nature of the press ...

2008

Study of N2O decomposition over Fe-ZSM-5 with transient methods

Petra Prechtl

Nitrous oxide is the third most important gas contributing to global warming and its concentration in the atmosphere is still on the rise. Nitric acid production represents the largest source of N2O in the chemical industry, with a total annual emission of ...

EPFL2007

Heterogeneous kinetics of some atmospherically relevant reactions

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The Real Carbon K-edge

Evaluated kinetic and photochemical data for atmospheric chemistry: Volume IV - gas phase reactions of organic halogen species

Nitrous Oxide Decomposition on the Binuclear $\left$ Center in Fe-ZSM-5 Zeolite

Sorption of hydrophobic organic compounds (HOC) in rapeseed oil bodies

Study of gaseous interactions in carbon nanotube field-effect transistors through selective Si(3)N(4) passivation

Formulation reproducing the ignition delays simulated by a detailed mechanism: Application to n-heptane combustion

Quantum calculations on the acid catalyzed rearrangements of norborn-5-en-2-one, 7-oxanorborn-5-en-2-one and 7-azanorborn-5-en-2-one - The electron-releasing effect of homoconjugated carbonyl group

Molecular relaxation effects in hydrogen chloride photoacoustic detection

Immobilization of rapeseed press-cake in an alginate matrix for the sorption of atrazine

Study of N2O decomposition over Fe-ZSM-5 with transient methods

The Real Carbon K-edge

Formulation reproducing the ignition delays simulated by a detailed mechanism: Application to n-heptane combustion

Evaluated kinetic and photochemical data for atmospheric chemistry: Volume IV - gas phase reactions of organic halogen species

Quantum calculations on the acid catalyzed rearrangements of norborn-5-en-2-one, 7-oxanorborn-5-en-2-one and 7-azanorborn-5-en-2-one - The electron-releasing effect of homoconjugated carbonyl group

Nitrous Oxide Decomposition on the Binuclear $\left$ Center in Fe-ZSM-5 Zeolite

Immobilization of rapeseed press-cake in an alginate matrix for the sorption of atrazine

Sorption of hydrophobic organic compounds (HOC) in rapeseed oil bodies

Molecular relaxation effects in hydrogen chloride photoacoustic detection

Study of N2O decomposition over Fe-ZSM-5 with transient methods

Study of gaseous interactions in carbon nanotube field-effect transistors through selective Si(3)N(4) passivation