Charge-coupled deviceA charge-coupled device (CCD) is an integrated circuit containing an array of linked, or coupled, capacitors. Under the control of an external circuit, each capacitor can transfer its electric charge to a neighboring capacitor. CCD sensors are a major technology used in digital imaging. In a CCD , pixels are represented by p-doped metal–oxide–semiconductor (MOS) capacitors.
Thermodynamic free energyIn thermodynamics, the thermodynamic free energy is one of the state functions of a thermodynamic system (the others being internal energy, enthalpy, entropy, etc.). The change in the free energy is the maximum amount of work that the system can perform in a process at constant temperature, and its sign indicates whether the process is thermodynamically favorable or forbidden. Since free energy usually contains potential energy, it is not absolute but depends on the choice of a zero point.
Terrestrial TimeTerrestrial Time (TT) is a modern astronomical time standard defined by the International Astronomical Union, primarily for time-measurements of astronomical observations made from the surface of Earth. For example, the Astronomical Almanac uses TT for its tables of positions (ephemerides) of the Sun, Moon and planets as seen from Earth. In this role, TT continues Terrestrial Dynamical Time (TDT or TD), which succeeded ephemeris time (ET). TT shares the original purpose for which ET was designed, to be free of the irregularities in the rotation of Earth.
TetraphenylporphyrinTetraphenylporphyrin, abbreviated TPP or H2TPP, is a synthetic heterocyclic compound that resembles naturally occurring porphyrins. Porphyrins are dyes and cofactors found in hemoglobin and cytochromes and are related to chlorophyll and vitamin B12. The study of naturally occurring porphyrins is complicated by their low symmetry and the presence of polar substituents. Tetraphenylporphyrin is hydrophobic, symmetrically substituted, and easily synthesized.
Coordinated Universal TimeCoordinated Universal Time or UTC is the primary time standard by which the world regulates clocks and time. It is within about one second of mean solar time (such as UT1) at 0° longitude (at the IERS Reference Meridian as the currently used prime meridian) and is not adjusted for daylight saving time. It is effectively a successor to Greenwich Mean Time (GMT). The coordination of time and frequency transmissions around the world began on 1 January 1960.
Coordinate timeIn the theory of relativity, it is convenient to express results in terms of a spacetime coordinate system relative to an implied observer. In many (but not all) coordinate systems, an event is specified by one time coordinate and three spatial coordinates. The time specified by the time coordinate is referred to as coordinate time to distinguish it from proper time.
Grand potentialThe grand potential or Landau potential or Landau free energy is a quantity used in statistical mechanics, especially for irreversible processes in open systems. The grand potential is the characteristic state function for the grand canonical ensemble. Grand potential is defined by where U is the internal energy, T is the temperature of the system, S is the entropy, μ is the chemical potential, and N is the number of particles in the system.
Unit of timeA unit of time is any particular time interval, used as a standard way of measuring or expressing duration. The base unit of time in the International System of Units (SI), and by extension most of the Western world, is the second, defined as about 9 billion oscillations of the caesium atom. The exact modern SI definition is "[The second] is defined by taking the fixed numerical value of the cesium frequency, ΔνCs, the unperturbed ground-state hyperfine transition frequency of the cesium 133 atom, to be 9 192 631 770 when expressed in the unit Hz, which is equal to s−1.
Inner sphere electron transferInner sphere electron transfer (IS ET) or bonded electron transfer is a redox chemical reaction that proceeds via a covalent linkage—a strong electronic interaction—between the oxidant and the reductant reactants. In inner sphere electron transfer, a ligand bridges the two metal redox centers during the electron transfer event. Inner sphere reactions are inhibited by large ligands, which prevent the formation of the crucial bridged intermediate. Thus, inner sphere ET is rare in biological systems, where redox sites are often shielded by bulky proteins.
PorphyriaPorphyria is a group of liver disorders in which substances called porphyrins build up in the body, negatively affecting the skin or nervous system. The types that affect the nervous system are also known as acute porphyria, as symptoms are rapid in onset and short in duration. Symptoms of an attack include abdominal pain, chest pain, vomiting, confusion, constipation, fever, high blood pressure, and high heart rate. The attacks usually last for days to weeks. Complications may include paralysis, low blood sodium levels, and seizures.
