Adsorption de polycarboxylates et de lignosulfonates sur poudre modèle et ciments
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During the last 20 years, backscattered electron imaging of polished surfaces has become well established as a method for the study of cement and concrete microstructures. The technique has many advantages, including the visualisation of representative cro ...
The strength of fusion bonds between polyamide 12 plaques has been investigated as a function of processing conditions, using the double cantilever beam geometry to measure the mode I critical strain energy release rate, GC. Bonding was carried out using a ...
Backscattered electron (BSE) images of heat-cured concretes show alite grains surrounded by inner C-S-H gel of two distinct grey levels (referred to as two-tone inner C-S-H gel). The lighter rim forms at elevated temperature whereas the darker rim develops ...
Delayed ettringite formation (DEF) can damage concrete that has experienced a temperature above about 70°C. Claims that slow release of sulfate from the clinker can have a similar effect in concrete not thus heated are unsupported. Chemical and microstruct ...
A family of cationic polyelectrolytes possessing defined chain lengths, narrow chain length distributions, uniform charge d., but substituents of different hydrophilicity at the quaternary ammonium group served as model compds. for adsorption studies. Thes ...
This paper describes the so called interfacial transition zone - ITZ - in concrete. This is the region of the cement paste around the aggregate particles, which is perturbed by the presence of the aggregate. Its origin lies in the packing of the cement gra ...
Poly(vinylbenzylammonium chloride) (PVBAC) polyelectrolytes possessing defined chain lengths, narrow chain length distributions, uniform charge d., but substituents of different hydrophilicity and size at the quaternary ammonium group were used as model co ...
NOVELTY - A hydraulic binder comprises a source of calcium aluminate, calcium silicate, sulfate, and a source of reactive silica. The ingredients are present in such relative proportions that, upon hydration, both monosulfate and hydrated alumina are forme ...
The overall topic of the investigation was the sepn. of basic proteins by cation exchange displacement chromatog. For this purpose two principal column morphologies were compared for the sepn. of RNase A and a-chymotrypsinogen, two proteins found in the bo ...
Comprehensive counterion activity studies have revealed clear influence of the polyelectrolyte concn. and chain length on the polyion-counterion interaction, neither of which is evident from the existing theor. models. The counterion activity coeff. (fa) i ...