Magnetic domainA magnetic domain is a region within a magnetic material in which the magnetization is in a uniform direction. This means that the individual magnetic moments of the atoms are aligned with one another and they point in the same direction. When cooled below a temperature called the Curie temperature, the magnetization of a piece of ferromagnetic material spontaneously divides into many small regions called magnetic domains. The magnetization within each domain points in a uniform direction, but the magnetization of different domains may point in different directions.
Spin states (d electrons)Spin states when describing transition metal coordination complexes refers to the potential spin configurations of the central metal's d electrons. For several oxidation states, metals can adopt high-spin and low-spin configurations. The ambiguity only applies to first row metals, because second- and third-row metals are invariably low-spin. These configurations can be understood through the two major models used to describe coordination complexes; crystal field theory and ligand field theory (a more advanced version based on molecular orbital theory).
Zeeman effectThe Zeeman effect (ˈzeɪmən; ˈzeːmɑn) is the effect of splitting of a spectral line into several components in the presence of a static magnetic field. It is named after the Dutch physicist Pieter Zeeman, who discovered it in 1896 and received a Nobel prize for this discovery. It is analogous to the Stark effect, the splitting of a spectral line into several components in the presence of an electric field.
Interplanetary magnetic fieldThe interplanetary magnetic field (IMF), now more commonly referred to as the heliospheric magnetic field (HMF), is the component of the solar magnetic field that is dragged out from the solar corona by the solar wind flow to fill the Solar System. The coronal and solar wind plasmas are highly electrically conductive, meaning the magnetic field lines and the plasma flows are effectively "frozen" together and the magnetic field cannot diffuse through the plasma on time scales of interest.
Band gapIn solid-state physics and solid-state chemistry, a band gap, also called a bandgap or energy gap, is an energy range in a solid where no electronic states exist. In graphs of the electronic band structure of solids, the band gap refers to the energy difference (often expressed in electronvolts) between the top of the valence band and the bottom of the conduction band in insulators and semiconductors. It is the energy required to promote an electron from the valence band to the conduction band.
Spin-1/2In quantum mechanics, spin is an intrinsic property of all elementary particles. All known fermions, the particles that constitute ordinary matter, have a spin of 1/2. The spin number describes how many symmetrical facets a particle has in one full rotation; a spin of 1/2 means that the particle must be rotated by two full turns (through 720°) before it has the same configuration as when it started. Particles having net spin 1/2 include the proton, neutron, electron, neutrino, and quarks.
Tensor productIn mathematics, the tensor product of two vector spaces V and W (over the same field) is a vector space to which is associated a bilinear map that maps a pair to an element of denoted An element of the form is called the tensor product of v and w. An element of is a tensor, and the tensor product of two vectors is sometimes called an elementary tensor or a decomposable tensor. The elementary tensors span in the sense that every element of is a sum of elementary tensors.
Crystal field theoryIn molecular physics, crystal field theory (CFT) describes the breaking of degeneracies of electron orbital states, usually d or f orbitals, due to a static electric field produced by a surrounding charge distribution (anion neighbors). This theory has been used to describe various spectroscopies of transition metal coordination complexes, in particular optical spectra (colors). CFT successfully accounts for some magnetic properties, colors, hydration enthalpies, and spinel structures of transition metal complexes, but it does not attempt to describe bonding.
Landau quantizationIn quantum mechanics, Landau quantization refers to the quantization of the cyclotron orbits of charged particles in a uniform magnetic field. As a result, the charged particles can only occupy orbits with discrete, equidistant energy values, called Landau levels. These levels are degenerate, with the number of electrons per level directly proportional to the strength of the applied magnetic field. It is named after the Soviet physicist Lev Landau. Landau quantization is directly responsible for the electronic susceptibility of metals, known as Landau diamagnetism.
