Screening for Refrigerant Blends in High-Temperature Lift Heat Pumps for Retrofit in Residential Heating

Providing heat pumps for the retrofit of fuel based boilers in residential heating, is a short or medium term challenge and a major opportunity for a substantial reduction of greenhouse gas emissions. While effective solutions for improved high temperature lift, vapor compression heat pumps have been analyzed elsewhere, this paper specifically deals with the refrigerant selection aspects for alternative blends, using a multi-objective optimization algorithm. The objectives COP and specific heat output are calculated for arbitrarily mixed refrigerant blends, using 17 selected pure fluids. Seasonal mean operating conditions (ambient air 0°C, heating water 50°C) have been used to simulate the heat pump cycle. Blends with a saturation curve extending over the range of –20°C (normal boiling point) and 70°C (critical point) are considered. Alternative blends are compared with the commercial mixture R-407C. The refrigerant mixture with the highest COP shows an improvement of 8% on the low capacity end of the Pareto-optimum curve. By maximizing the specific heat rate, a gain of 83% can be achieved. All the dominating solutions are composed of flammable refrigerants.

Wärmepumpe mit Zwischeneinspritzung bei Scrollkompressoren.

Daniel Favrat, Michele Zehnder

This project is evaluating a heat pump cycle with midstage injection at scroll compressors. The injected refrigerant is evaporated partially by an internal heat exchanger (fig. 2.1). A glycol-water heat pump with 12 kW heat capacity at B-5/W50 was built and tested in the laboratory at several conditions (B- 5/0/5 at W35/50 and B-10/W60). The refrigerant is R407C. For the theoretical analysis the exact geometry of the injection wholes is determined. The results are discussed in the hypothesis of a monovalent heating implementation in the market of retrofitting fuel based heating systems. Measurements at stationary test conditions with injection show an increase of the heat output by 15% compared to the values without injection (fig 4.2 and 4.5). The heat output is not affected by the position of the manually regulated injection valve. The end of compression temperature can be controlled by the amount of injected refrigerant. The application range for this heat pump is enlarged and at the point B-10/W60 the maximum system temperature has been reduced from 110°C to 75°C. The coefficient of performance (COP) with and without injection is comparable at the major part of the tested points (fig. 4.1 and 4.4). The only available compressor type with the possibility of injection has a geometry which is not adapted for saturated vapor. The resulting reduction in performance is equivalent to the gain by the better thermodynamic concept. The optimum COP is reached with an injection rate issued by a thermostatic valve control. With higher injection rate, the COP is decreasing linearly and a reduction up to 15% is achieved at B-10/W60. Two injection configurations (the injected refrigerant is separated before and after the economizer exchanger) have been compared and show equivalent results. The simulation model has been developed considering the test results. For the compression phase during injection a correction factor has been introduced. The simulation can be used to analyse of the qualitative behavior. A high potential of performance improvement can be achieved by reducing the injection pressure level (table 5.2). Shifting the position of the injection wholes in higher pressure regions does not affect the performances but can keep the compression curve away from the saturation limit.

2000

Analyse de la migration d’huile dans les pompes à chaleur mono- et biétagées

Daniel Favrat, Michele Zehnder

The Laboratory of Industrial Energy systems has evaluated a series of high performance air-water heat pump concepts with the aim to retrofit existing fuel fired boilers for residential hydronic heating systems. The results are published within the framework of the Swiss Retrofit Heat Pump project, which is conducted by the Swiss Federal Office of Energy. The two-stage heat pump cycle has shown the best efficiency prospects. Oil migration between the upper stage and lower stage compressors is the main obstacle for commercialization in the low heat rate range. The oil mass concentration is measured by the Fourier Transform Infrared Spectrospopy (FTIR) method with an attenuated total reflection cell (ATR). This method was calibrated on a separated test loop and compared to measurements of mass-sampling and of density by a Coriolis effect densitymeter. Infrared analysis gives a precision of < 0.1% of oil concentration and the detection limit was identified at about 0.3%. Density measurements cannot be used in the ordinary temperature range of the liquid line in the heat pump. Mass sampling and the FT-IR measurements give corresponding results. An air-water heat pump (10 kWth, R-407C) was build in the laboratory to perform comparison tests in the single-stage and two-stage heating modes. The main elements of the heat pump are: two scroll type compressors, a brazed plate condenser, a finned tube evaporator, an economizer heat exchanger and two electronic expansion valves. Defrosting is done by cycle inversion with a 4-way reversing valve. Measured improvements on the two-stage heating mode of 30% for the COP and 24% for the heat output comparing to the corresponding test point (A-7/W50) in the single stage configuration have been shown. Important reductions of the maximum system temperature at the outlet of the compressors enable an extended range of application (including the point A-12/W65). In the two-stage heating mode an oil transfer rate of 5 - 10 g/min from the high pressure stage to the low pressure stage compressor was detected in all tested conditions, which is strongly limiting the continuous service of the heat pump. For long term running tests an additional balancing system composed of an oil pump and an oil vessel has been installed. The circulating oil concentration is between 0.2% and 0.4% for the two-stage configuration as measured with the FT-IR method. In single-stage mode the concentration is lower than 0.2% and only the mass sampling technique provided reliable results. Sensibility analysis in changing the regulation parameters did not give concluding results in order to design a stable configuration of the two-stage heat pump. In absence of integrated two-stage scroll compressors intermediate solutions have to be considered. These consist in the implementation of a booster compressor or the implementation of an oil separator at the outlet of the high pressure stage compressor coupled with a oil return management or a periodic shut down of the heat pump with external balancing of the oil level in the crankcase. An adapted heat transfer model for refrigerant-oil mixtures was developed, in order to investigate the theoretical impact of oil in the evaporator.

2003

Analyse de la migration d’huile dans les pompes à chaleur mono- et biétagées

Daniel Favrat, Michele Zehnder

2003

Wärmepumpe mit Zwischeneinspritzung bei Scrollkompressoren.

Daniel Favrat, Michele Zehnder

2000