Absolute Standard Redox Potential of Monolayer-Protected Gold Nanoclusters
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The electrochemical oxidation of 3,4-(methylenedioxy)phenylmethanol (piperonyl alcohol) was characterized by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Two electrochemical oxidation signals were found for piperonyl alcohol. T ...
The interface between two immiscible electrolyte solutions (ITIES), or liquid|liquid interface, provides a defect-free junction for fundamental studies of adsorption phenomena, heterogeneous charge transfer reactions, and phase-formation processes. Recent ...
Electro-oxidn. of platinum film electrode deposited on yttria-stabilized zirconia (YSZ) is examd. in situ using potential programmed voltammetry at 450 DegC in oxygen contg. atm. Under prolonged anodic oxidn. different sorts of oxidized species are formed ...
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Dimensionally Stable Anodes (DSA®) are electrodes composed of a metal support and an oxide coating (catalyst). Particularly in this thesis, the Ti/IrO2 electrode was used for the study of the fraction of the surface which participates effectively in the in ...
The redox properties of a monolayer of alkanethiolate-protected gold nanoclusters (MPCs) constructed on a gold slide electrode was studied in 1,2-dichloroethane (DCE) electrolyte solutions. The influence of the electrostatic interaction between attached MP ...
The chemical-mechanical polishing process (CMP) is an essential part of the production of integrated circuits. Metal to be polished in the CMP reacts with the oxidants from the aqueous suspension (slurry) and the passive film is formed on the metal surface ...
The supramolecular assembly of Ru-bipyridine complex, coded Z-907Na, with single-walled carbon nanotube (SWNT) exhibits unique redox behavior, which is applicable for the nanotube wiring of LiFePO4 (olivine). Cyclic voltammograms of thin films of Z-907Na/S ...
An experimental setup to study the pH dependence of standard ion-transfer potentials at the water/NPOE interface is presented. The system is composed of a micro-hole generated by laser photoablation in a 12-μm polyethylene terephthalate film, the aqueous p ...
Biased Born-Oppenheimer molecular dynamics simulations are performed to compute redox potential and free energy curves for the redox half reaction Ag(+)-->Ag(2+)+e(-) in aqueous solution. The potential energy surfaces of reactant and product state are line ...