Reactivity of Monolayer-Protected Gold Nanoclusters at Dye-Sensitized Liquid/Liquid Interfaces
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The voltage induced assembly and photoreactivity of cadmium selenide (CdSe) nanoparticles protected by mercaptosuccinic acid are studied at the polarisable interface between water and 1,2-dichloroethane electrolyte solutions. Cyclic voltammograms and admit ...
The interface between two immiscible electrolyte solutions provides a well-defined framework for fundamental studies of heterogeneous charge transfer processes. Recent developments in experimental methodology have allowed addressing the kinetics of electro ...
Due to their high efficiencies and their potentially low production costs, dye-sensitized solar cells (DSSC) have attracted much attention during the last few years. The technology is based on a layer made of mesoscopic TiO2 film which significantly increa ...
Dye-sensitized photoelectrochem. solar cells constitute a promising candidate in the search for cost-effective and environment-friendly solar cells. The most extensively studied, and to date the most efficient systems are based on titanium dioxide. In this ...
The dynamics of photoresponses associated with heterogeneous quenching of zinc tetrakis(carboxphenyl)porphyrin (ZnTPPC) and ferrocene derivatives at the water/1,2-dichloroethane interface were studied by intensity modulated photocurrent spectroscopy (IMPS) ...
The dye solar cell, is a novel photoelectrochemical solar cell presenting unique advantages, as the use of low cost materials and the potential simplicity of manufacturing. However, a liquid electrolyte is actually required for the transport of the photoge ...
The oxidative degrdn. rate, kdeg, of the solar cell dye (Bu4N+)2[Ru(dcbpyH)2(NCS)2]2-, referred to as N719 or [RuL2(NCS)2], was obtained by applying a simple model system. Colloidal solns. of N719-dyed TiO2 particles in acetonitrile were irradiated with 53 ...
The photoelectrochemical properties of TiO2 anatase nanoparticles were studied at the water|1,2-dichloroethane (DCE) interface under potentiostatic control. The interfacial concentration of the electrostatically stabilized particles can be effectively tune ...
Photoelectron spectroscopy is used to measure the electronic d. of states in the band gap region of a nanostructured TiO2 film. Such nanostructured films are used in dye-sensitized solar cells, and a plain TiO2 film as well as a dye-sensitized film were ex ...
Fundamental expressions for analyzing potential modulated fluorescence (PMF) responses were derived within the framework of a phenomenological model for adsorption and transfer of ionic species across polarized liquid|liquid interfaces. For small periodic ...