Total asymmetric synthesis of (-)-conduramine B-1 and of its enantiomer. N-Benzyl derivatives of conduramine B-1 are beta-glucosidase inhibitors
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We tested the theoretical prediction that the band structures on the opposite sides of a homojunction can be artificially displaced in energy with respect to each other by means of double intralayers of atomiclike thickness, producing band discontinuities ...
The photochem. of colloidal ZnS was studied under a variety of exptl. conditions. The time dependence of the photocorrosion was examd. by using time-resolved fluorescence, static fluorescence, and electrospectroscopy for chem. anal. (ESCA) techniques. A qu ...
The kinetics of an enzymic transesterification reaction were studied by considering a model reaction: the transesterification of a racemic mixt. of phenylalanine Pr ester with 1,4-butanediol by chymotrypsin (EC 3.4.21.1). The model developed, describing th ...
The structure and absolute configuration of natural lentiginosine isolated from plant sources was determined to be (1S,2S,8aS)-1,2-dihydroxyindolizidine ((+)-4) on the basis of the synthesis of both enantiomers (+)-4 and (-)-4 and their inhibition of amylo ...
N-[2-(hydroxymethyl)phenyl]pyrrole was found to be amenable to selective a-metalation. Trapping with a variety of electrophilic reagents afforded the expected products with moderate to high yields. Derivs. formed by treatment of the organometallic intermed ...
Epi-b-santalene (I; R = H), readily accessible in both enantiomeric forms, was regio- and stereoselectively converted into (R)-(-)- or (S)-(+)-(Z)-epi-b-santalol (I; R = OH) by consecutive metalation, borylation and oxidn. [on SciFinder (R)] ...
