Information extraction from the Evolving Factor Analysis
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The reaction of 4-methoxy-1,2,3,4-tetrahydroisoquinolines I (R = MeO, R1 = H; RR1 = OCH2O) with Li diisopropylamide affords dimerization products II. The intermediacy of orthoquinodimethanes and diradicals is assumed. [on SciFinder (R)] ...
This dissertation is concerned with the development of a methodology and appropriate tools for the investigation of chemical reaction systems using measured data. More specifically, the determination of reaction stoichiometry and kinetics from concentratio ...
Abstract The objective of this work is the numerical simulation of the reactive laminar boundary layer which occurs in a neighbourhood of a body moving in the air. We have investigated the modelling of the reactive boundary layer when, the "chemical equili ...
Calibration is the first step in the prediction of concentrations from spectral measurements of chemical reaction systems. It is a well-known fact that the species in the calibration set must include those in the new set. Typically, the calibration set is ...
The concept of reaction invariants is extended to include flow invariants of chemical-reaction systems with inlet and outlet streams. A transformation to normal form is introduced that allows the separation of (1) the evolution of the independent reactions ...
An account of our most recent studies on the application of high pressure kinetic techniques in mechanistic studies of inorganic reactions is presented. The investigated reactions include substitution, addition, insertion, elimination, electron-transfer, p ...
High quality pseudomorphic Si1-yCy and Si1-x-yGexCy layers were grown on (100) Si between 530 and 650 degrees C by rapid thermal chemical vapor deposition in the SiH4/GeH4/SiH3CH3/H-2 system. These layers contained up to 30 at. % Ge and up to 2.2 at. % C. ...
A method for solving periodic optimization problems is introduced. The method is based on the T. Carleman (1932) linearization procedure of lumped-parameter system and may be used to det. the optimal pulse periodic input. The method is employed to study 2 ...
We identified the nature of the chemical reaction between silver and the cleaved surface of BiCaSrCuO at room temperature as a Bi-Ag reaction with Bi segregation, accompanied by interaction with the Sr atoms. Our synchrotron-radiation photoemission spectra ...
We explored the reactivity of gold on cleaved 2212 BiCaSrCuO by synchrotron-radiation photoemission spectroscopy. We found no evidence for reactivity when the substrate was at room temperature, similar to what has been reported for very low temperatures (2 ...
