Syntheses and catalytic applications of immobilized ruthenium complexes
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Homo- and heterobimetallic complexes of the late transitions metals have been synthesized by metathesis reactions of the corresponding chloro-bridged dimers. These reactions have the advantage of being fast and giving rise to structurally defined products ...
The bimetallic ruthenium complex [(1,3,5-C6H3i-Pr3)Ru(m-Cl)3RuCl(C2H4)(PCy3)] has been synthesized by reaction of [(1,3,5-C6H3i-Pr3)RuCl2)]2 with one equivalent of PCy3 in the presence of ethylene. It can be used as a catalyst precursor for the controlled ...
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A bimetallic complex, in which a RuCl2 (eta(2)C(2)H(4))(PCy3) fragment is connected via three chloro, bridges to a (eta(6)-p-cymene)RuCl2 fragment, has been synthesized and characterized by single-crystal X-ray crystallography. This complex was used to cat ...
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Pure and K-doped vanadia/titania catalysts have been studied by transient response method and in situ DRIFTS during toluene partial oxidn. They were characterized by FT-Raman spectroscopy, TPR, TPD of pyridine and XPS. In order to elucidate the role of dif ...
