The effect of alkali hydroxides and equilibration time on Al uptake by calcium silicate hydrates (C-S-H)

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Atomic-Level and Surface Structure of Calcium Silicate Hydrate Nanofoils

Karen Scrivener, Paul Bowen, Aslam Kunhi Mohamed, Ziga Casar

Deciphering the calcium silicate hydrate (C-S-H) surface is crucial for unraveling the mechanisms of cement hydration and property development. Experimental observations of C-S-H in cement systems suggest a surface termination which is fundamentally differ ...

AMER CHEMICAL SOC2023

Atomistic modeling of C-S-H: bulk and surface

Ziga Casar

By replacing part of Portland cement with so-called supplementary cementitious materials (SCMs) it is possible to reduce the CO2 footprint of the cement industry. These SCMs are commonly limestone, calcined clay, slag and fly ash. While doing so the early ...

EPFL2023

Going Below 50% Clinker Factor in Limestone Calcined Clay Cements (LC3): A Comparison with Pozzolanic Cements from the South American Market

Karen Scrivener, Franco Alberto Zunino Sommariva

Limestone calcined clays are a promising technology as they offer similar performance to OPC from 7 days onwards, while enabling a reduction of the clinker content of 50%. In some regions of the world like South America, pozzolanic cements (i.e., blended c ...

SPRINGER INTERNATIONAL PUBLISHING AG2023

Data-driven optimization tool for the functional, economic, and environmental properties of blended cement concrete using supplementary cementitious materials

Hisham Tarek Mohamed Hafez

The need to produce more sustainable concrete is proving imminent given the rising environmental concerns facing the industry. Blended cement concrete, based on any of the prominent supplementary cementitious materials (SCMs) such as fly ash, ground granul ...

ELSEVIER2023

Durability Challenges of Low-Grade Calcined Clay Opposed to High-Volume Fly Ash in General Purpose Concrete

Karen Scrivener, Matea Flegar

With the decrease in availability of common supplementary cementitious materials (SCMs) such as fly ash in Europe, the search for appropriate SCMs should be dealt with locally. A com-bination of abundant low-grade calcined clay and limestone powder has pro ...

AMER SOC TESTING MATERIALS2023

A multi-model analysis of the EU’s path to net zero

Marc Vielle, Sigit Pria Perdana

The European Union (EU) recently ratcheted its climate ambition to net-zero emissions by 2050, with a milestone of 55% emissions cuts in 2030. This study carries out a model inter-comparison to assess the EU’s path, from “Fit for 55” in 2030 to an intermed ...

2023

Upper bounds on technoemission rates from 60 years of "silence"

Claudio Grimaldi

The lack of detection to date of electromagnetic technosignatures implies either that we have been unable to detect them due to incomplete sampling of the search space or that we cannot detect them because the Earth has been located during the entire histo ...

PERGAMON-ELSEVIER SCIENCE LTD2023

Characterisation and hydration kinetics of beta-C2S synthesised with K2SO4 as dopant

Karen Scrivener, Franco Alberto Zunino Sommariva, Shashank Bishnoi, Sreejith Krishnan

In this study, a protocol for synthesising beta-C2S using K2SO4 as a dopant has been reported. Quantitative X-Ray diffraction was used to characterise synthesised samples. It was observed that it is possible to synthesise beta-C2S with high purity (>96 wt% ...

Pergamon-Elsevier Science Ltd2023

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