Publication

Stabilization of molecular LiF, LiFHF, and Na2SiF6 using metallamacrocyclic hosts

Kay Severin
2003
Journal paper

Abstract

The molecular forms of LiF, LiFHF and Na2SiF6 have been stabilized using trinuclear metallamacrocyclic complexes of (cymene)Ru-II, (Cp*)Rh-III and (Cp*)Ir-III as specific receptors. The host-guest complexes were characterized by NMR spectroscopy and single crystal X-ray diffraction. Based on these results, a highly selective chemosensor for fluoride anions has been developed.

Official source

https://infoscience.epfl.ch/record/76717?ln=en

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Stabilization of molecular LiF, LiFHF, and Na2SiF6 using metallamacrocyclic hosts

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