The reaction volume for the equilibrium between the lanthanide(III) ennea- and octaaqua ions as a diagnostic aid for their water-exchange mechanisms
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The generation of α-ferrocenyl carbocations from ferrocenyl alcohols for SN1 substitution at the water–organic solvent interface is initiated by the transfer of protons into the organic phase. The proton flux, and hence the reaction rate, can be controlled ...
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