Publication

Inductive and polarizability effects of an exocyclic diene-iron tricarbonyl group. The acetolyses of exo- and endo-irontricarbonyl complexes of 5,6-dimethylidene-2-exo-norbornyl and 2,3-dimethylidene-7-anti-norbornyl parabromobenzenesulfonates

Related publications (34)

Incremental Model Identification of Reaction Systems

Identification of kinetic models is an important task for monitoring, control and optimization of industrial processes. Robust kinetic models are often based on first principles, which describe the evolution of states – number of moles, temperature and vol ...

2013

Speciation-dependent kinetics of uranium(VI) bioreduction

Rizlan Bernier-Latmani, Harish Veeramani

The kinetics of uranium(VI) reduction by Shewanella oneidensis strain MR-1 was studied for varied pH and concentrations of dissolved inorganic carbon (DIC) and calcium. These are key variables affecting U(VI) speciation in aqueous systems. For all conditio ...

Taylor & Francis2011

Experimental validation of control rod related perturbations of moderator regions in an SCWR-like fuel lattice

Rakesh Chawla

Two different types of perturbations of an SCWR-like fuel lattice have been investigated experimentally in the central test zone of the PROTEUS zero-power research reactor at the Paul Scherrer Institute in Switzerland. In each case, a campaign of high-reso ...

Elsevier2011

Global sensitivity analysis for model-based prediction of oxidative micropollutant transformation during drinking water treatment

Urs von Gunten

This study quantifies the uncertainty involved in predicting micropollutant oxidation during drinking water ozonation in a pilot plant reactor. The analysis is conducted for geosmin, methyl tert-butyl ether (MTBE), isopropylmethoxypyrazine (IPMP), bezafibr ...

2009

Supertough UV-curable silane/silica gas barrier coatings on polymers

Yves Leterrier, Bandeep Singh, Gil Rochat

Ultra-thin (10–500 nm) photo-polymerized γ-methacryloxypropyltriethoxysilane (MPMS) and vinyltrimethoxysilane (VTS) layers applied to SiO2 coatings on polyethylene terephthalate films improved the oxygen barrier performance of the oxide coated films by mor ...

Elsevier2009

Uncertainties in kinetic hard-modelling of multivariate spectroscopic data

Julien Léo Billeter, Konrad Hungerbühler

Kinetic hard-modelling of multivariate spectroscopic data [1, 2] is a well-established method for the determination of reaction mechanisms and associated rate constants. Kinetic hard-modelling relies on a hard model defined by kinetic rate laws and require ...

2008

Uncertainties and error propagation in kinetic hard-modelling of spectroscopic data

Julien Léo Billeter, Konrad Hungerbühler

A novel method is presented for the rigorous propagation of uncertainties in initial concentrations and in dosing rates into the errors in the rate constants fitted by multivariate kinetic hard-modelling of spectroscopic data using the Newton–Gauss–Levenbe ...

Elsevier2008

Oxidation kinetics of selected taste and odor compounds during ozonation of drinking water

Urs von Gunten

The applicability of ozonation to mitigate taste and odor problems in drinking water was investigated. Second-order rate constants of eleven taste and odor compounds with ozone and hydroxyl radicals were determined under laboratory conditions. Measured rat ...

2007

Synthesis of monodispersed palladium nanoparticles to study structure sensitivity of solvent-free selective hydrogenation of 2-methyl-3-butyn-2-ol

Albert Renken, Lioubov Kiwi, Danièle Laub

A novel method for isolation of monodispersed Pd nanoparticles from a reverse microemulsion was developed using hydrocarbon evaporation and methanol-assisted particle purification from a surfactant. Fcc Pd nanoparticles of 6, 8, 11, and 13 nm in diameter w ...

2007

Kinetics and mechanistic aspects of As(III) oxidation by aqueous chlorine, chloramines, and ozone: Relevance to drinking water treatment

Urs von Gunten

Kinetics and mechanisms of As(III) oxidation by free available chlorine (FAC-the sum of HOCl and OCl-), ozone (O-3), and monochloramine (NH2Cl) were investigated in buffered reagent solutions. Each reaction was found to be first order in oxidant and in As( ...

2006

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