Structure and characterization of CI3+[Al{OC(CF3)3}4]-; Lewis acidities of CX3+ and BX3
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Monitoring, control and optimization of chemical reaction systems often requires in-depth analysis of the underlying reaction mechanisms. This dissertation investigates appropriate tools that facilitate the analysis of homogeneous and gas-liquid reaction s ...
With the aid of molecular simulation techniques (molecular dynamics, grand-canonical Monte Carlo, and reactive flux correlation function RFCF), the influence of the external surface on the equilibrium permeation of methane and ethane into and out of an AFI ...
We present a thorough Se-77 nuclear-magnetic-resonance (NMR) study of a single crystal of the magnetoelectric compound Cu2OSeO3. The temperature dependence of the local electronic moments extracted from the NMR data is fully consistent with a magnetic phas ...
The transition metal tellurium oxychloride, Ni-5(TeO3)(4)Cl-2, has been investigated by high-field electron-spin resonance for frequencies up to 3 THz, at temperatures well below the magnetic ordering at 23 K. At zero external field several resonance modes ...
Electron Beam Induced Deposition (EBID) allows deposition of three-dimensional micro- and nano-structures of conductive and insulating materials on a wide range of substrates. The process is based on the decomposition of molecules of a pre-selected precurs ...
Abstract: The connection of lipophilic gallic acid derivatives at the 5,5¢- or 6,6¢-positions of the rigid 2,6-bis(1-ethyl-benzimidazol-2-yl)pyridine core provides two pro-mesogenic tridentate ligands L10 and L12, whose molecular shapes, anisometries, and ...
Recently we reported on the synthesis and characterization of a series of very weakly coordinating anions (WCA's) of type Al(OR)4- (R=poly or perfluorinated aliph. alkoxide). These anions produce "Pseudo Gas Phase Conditions" in the solid state that allo ...
The reactivity of (E)- and (Z)-1-fluorobuta-1,3-diene ((E)- and (Z)-11), 2-fluorobutadiene (12). (E)and (Z)-1-(fluoromethylidene)-2-methylidenecyclohexane ((E)- and (Z)-13) toward SO2 has been explored and compared with that of (Z)- and (E)-1-(fluoromethyl ...
The structure of room-temperature ZrP2O7 is shown to be orthorhombic by a combination of high-resolution synchrotron powder diffraction and single-crystal synchrotron diffraction data. Small nontwinned single crystals were obtained by synthesizing the comp ...
We show here that by combining tailored approaches based on ultrafast (60 kHz) MAS on the Co-II-replaced catalytic domain of matrix metalloproteinase 12 (CoMMP-12) we can observe and assign, in a highly paramagnetic protein in the solid state, C-13 and eve ...