Organometallics versus P4 Complexes of Group 11 Cations: Periodic Trends and Relativistic Effects in the Involvement of (n-1)d, ns, and np Orbitals in Metal-Ligand Interactions
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The photophysical properties of the triple-stranded dimetallic helicates [Ln2(LC−2H)3]·H2O (Ln = Nd, Sm, Dy, Yb) are determined in water and D2O solutions, and energy transfer processes are modeled for SmIII. The luminescence of NdIII, SmIII, and YbIII is ...
Upon treating elemental S with [AgSbF6], [AgAl(hfip)4], [AgAl(pftb)4] (hfip = OCH(CF3)2, pftb = OC(CF3)3), [Ag(S8)2][SbF6] (1), [AgS8][Al(hfip)4] (2), and [Ag(S8)2]+[Al(pftb)4]- (3) formed in SO2 (1), CS2 (2), or CH2Cl2 (3). 1-3 Were characterized by singl ...
We have calculated the maximally localized Wannier functions of MnO in its antiferromagnetic (AFM) rhombohedral unit cell, which contains two formula units. Electron Bloch functions are obtained with the linearized-augmented-plane-wave method within both t ...
The photophysical properties of the triple-stranded dimetallic helicates [Ln2(LC−2H)3]·H2O (Ln = Nd, Sm, Dy, Yb) are determined in water and D2O solutions, and energy transfer processes are modeled for SmIII. The luminescence of NdIII, SmIII, and YbIII is ...
A review. The theor. modeling of chem. active transition metal (TM) centers is a notoriously difficult task. The metal-ligand interactions in these complexes are often highly directional and the concoction of suitable analytic interaction potentials can be ...
Carbamoyl phosphate (CP) has been implicated as an educt for the synthesis of the CO and CN ligands of the metal centre of [NiFe]-hydrogenases in Escherichia coli, since CP synthetase mutants (carAB) are unable to generate active hydrogenases due to a bloc ...
The invention provides a novel podate ligand H4L[1,2,4,5-tetrakis(pyrazol-1-ylmethyl-3-carboxylic acid)benzene] and to complexes comprising the ligand and a metal ion. Pharmaceutical compositions and methods of making and using the metal-podate complex ...
For the low-spin t2g6 Ru(OH2)62+ (ΔV⧧ = −0.4 cm3 mol-1) and Rh(OH2)63+ (ΔV⧧ = −4.2 cm3 mol-1) hexaaquaions, the respective Id and Ia water exchange mechanisms had been assigned, mainly on the basis of activation volumes ΔV⧧ and entering ligands effects for ...
Metathesis reactions of dinuclear halo-bridged complexes of the late transition metals were studied by NMR. For selected combinations of 15 different complexes, asym. complexes are formed in a dynamic equil. The equil. consts. were calcd. and the trends th ...
The reaction of (E)-bis(2,4,6-tri-tert-butylphenyl)diphosphene with Ru-3(CO)(12) results in cleavage of the P=P bond with concomitant C-H activation of one of the t-butyl groups to form Ru-3(mu-H)(2)(CO)(8)(mu-P-C6H2-2,4-Bu-t(2)-6-CMe2CH2)(2). The H-atoms ...