Electrocatalysis in anodic oxidation of organics with simultaneous oxygen evolution
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The electro-combustion of water sol. polymeric contaminants such as polyacrylates (PA) in aq. acid soln. using a B-doped diamond anode was studied by bulk electrolysis in 1 mol/dm3 HClO4 under galvanostatic conditions in a wide range of PA concns. and curr ...
In the electrolysis of a soln. contg. glucose, as a model substrate in the wastewater from food industry, and a dil. NaCl, the formation of active Cl makes the glucose mineralization at the stable DSA electrode substantially insensitive to the nature of th ...
The electrochem. oxidn. (or combustion) of orgs. with simultaneous oxygen evolution has been investigated using different oxide electrodes. A simplified mechanism for the electrochem. oxidn. of orgs. is presented, according to which selective oxidn. occurs ...
Among the numerous base metals tested for DSA type electrodes (e.g., titanium and its alloys, zirconium, niobium etc.), tantalum is a potentially excellent substrate owing to its good elec. cond. and corrosion resistance, and the favorable dielec. properti ...
The methoxylation of p-tert-butyltoluene (TBT) in CH3OH-H2SO4-H2O soln. has been investigated on graphite and boron-doped diamond (BDD) anodes. Different reaction intermediates have been found on BDD and graphite. In fact BDD electrodes favor the formation ...
A piezoelectric thin film sandwiched between two conductors is the basic structure for high frequency bulk acoustic wave devices. For that purpose, AlN thin films deposited by DC reactive sputtering on various electrode materials were investigated, Highly ...
The electrochem. oxidn. of EDTA was studied at boron-doped diamond (BDD) electrodes. Cyclic voltammetry in the potential region of water stability showed that EDTA is oxidized in an irreversible 2-electron-transfer mechanism. No fouling phenomena were noti ...
The Boron-Doped Diamond (BDD) electrode is a new electrode material with high stability, even at high anodic potential. Furthermore BDD is not prone to fouling. Due to these properties, BDD can provide new opportunities in electrochem. synthesis of org. an ...
IrO2 and boron-doped diamond electrodes were tested by preparative electrolysis of simple model compds. in acid medium. In oxidn. reactions of more complex mechanism than simple electron transfer, these electrodes are active only at potentials of simultane ...
Electrochem. oxidn. of orgs. at thermally prepd. dimensionally stable metal oxide anodes (DSA) has been studied. In reactions involving only simple electron transfer, oxide electrodes exhibit an electrocatalytic activity similar to that of noble metal elec ...