Chlorine evolution at highly boron-doped diamond electrodes
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The electrochem. oxidn. of 3-methylpyridine (3-MP) at synthetic boron-doped diamond (BDD) thin film electrode was studied in acid media by cyclic voltammetry and bulk electrolysis. The results showed that in the potential region of water stability there ca ...
The electrochem. oxidn. of phenol at synthetic boron-doped diamond thin film electrode (BDD) was studied in acid media by cyclic voltammetry, chronoamperometry, and bulk electrolysis. In the potential region of water stability (E
IrO2 and boron-doped diamond electrodes were tested by preparative electrolysis of simple model compds. in acid medium. In oxidn. reactions of more complex mechanism than simple electron transfer, these electrodes are active only at potentials of simultane ...
This work contributes to the generalization of the Non-faradaic Electrochemical Modification of Catalytic Activity effect, known under the acronym NEMCA. This effect is observed for the first time over an oxide catalyst, namely IrO2 supported on yttria-sta ...
The electrochemical promotion of heterogeneous catalytic reactions is a new development which draws the attention of the scientific community as much to fundamental research as to the possible direct applications of this phenomenon in automotive and in ind ...
Deposition of small amts. of IrO2 clusters on the B-doped diamond (BDD) surface (BDD-IrO2 electrode) dramatically enhances both the O2 evolution reaction and the oxidn. of orgs. in the potential region of water decompn. The fact that BDD-IrO2 electrode beh ...
