Electrochemical production of peroxodisulfuric acid using diamond coated electrodes
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The electropolishing of a B-doped diamond (BDD) film deposited by CVD was studied in HOAc-H2SO4 media. The electropolished surface was characterized by SEM, XPS, and electrochem. measurements. In 1 M H2SO4 no polishing of the surface occurred even after pr ...
A simple method is presented which allows to est. the facility of the electrochem. oxidn. of org. species using the electrochem. oxidizability index (EOI) and the degree of oxidn. using the electrochem. oxygen demand (EOD). At platinum anode only benzene d ...
Diamond films with different levels of doping have been the subject of applications and fundamental research in electrochemistry, opening up a new branch known as the electrochemistry of diamond. The electrochemical properties of diamond mostly depend on t ...
The aim was to examine the anodic oxidn. of some benzene derivs. (model org. pollutants) at Pt and DSA (dimensionally stable anodes) type anodes to elucidate the possibilities of the electrochem. method and to elucidate the mechanism of the reaction. ...
The electrocombustion technique has recently been proposed to oxidize nonbiodegradable org. pollutants such as chlorophenol. The authors considered two different types of electrode material: boron doped diamond (BDD) and lead dioxide electrodeposited on Ti ...
Synthetic boron-doped diamond (BDD) thin film electrodes were tested for the electrogeneration of silver(II). In nitric acid, the kinetics of the silver(I)/silver(II) couple were studied by cyclic voltammetry. The results demonstrate that silver(II) can be ...
The electrochem. oxidn. (or combustion) of orgs. with simultaneous oxygen evolution has been investigated using different oxide electrodes. A simplified mechanism for the electrochem. oxidn. of orgs. is presented, according to which selective oxidn. occurs ...
A theor. model describing the electrochem. oxidn. of orgs. at oxide electrodes (MOx) forming the higher oxide (Mox+1) is described. In this model, both orgs. and O2 evolution are mediated by the higher oxide (MOx+1) which is electrogenerated at the anode s ...
The electrochem. oxidn. of Mn(II) in H2SO4 (30% wt.) has been studied using cyclic voltammetry. The mechanism was shown to be of the type ECE (Electrochem.-Chem.-Electrochem.). The deposition of MnO2 on the anode can be avoided by inhibiting the chem. reac ...
A simple method is presented which allows to est. the facility of the electrochem. oxidn. of org. species using the "electrochem. oxidn. index" (EOI) and the degree of oxidn. using the "electrochem. oxygen demand" (EOD). Using this method the authors have ...
