Electrochemical oxidation of phenol at boron-doped diamond electrode. Application to electro-organic synthesis and wastewater treatment
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Boron doped diamond films have been deposited by large area hot-filament CVD (HFCVD) on silicon, silicon carbide, and different industrial electrode materials, like niobium, tantalum, titanium, tungsten, zirconium, and graphite on areas up to 40 cm * 60 cm ...
B-doped diamond films were deposited by large-area hot filament chem. vapor deposition (HFCVD) on Si and different industrial electrode materials, such as Ti, Zr, Nb, Ta, W, and graphite, with areas up to 50 * 60 cm2. B-doping levels ranging from 50 to sev ...
Electrochemistry can bring important contributions to current applications, such as organic synthesis or wastewater treatment. In an environmental context, electrochemical processes are interesting substitutes to the conventional wastewater treatment techn ...
Cyclic voltammetry for the ferri-ferrocyanide redox couple was used to study the Ti/SnO2-Sb2O5 electrode prepd. by spray-pyrolysis under different conditions. Increasing the prepn. temp. and the duration of coating deposition results in a decrease of ip an ...
Synthetic B-doped diamond thin film electrodes were tested for electroanal. detection of 2-naphthol. This redox reaction was studied by cyclic voltammetry in aq. acidic soln. Well-resolved oxidn. waves were obsd. and the voltammetric peaks exhibited naphth ...
Thin boron-doped diamond films were prepd. by HF CVD (hot filament chem. vapor deposition technique) on conductive p-Si substrate (Si/diamond). The morphol. of these Si/diamond electrodes was investigated by SEM and Raman spectroscopy. The electrochem. beh ...
The Cl2 evolution reaction was studied at highly boron-doped diamond thin film electrodes. The comparison of this carbonaceous material with graphite and glassy carbon points out the similar behavior in terms of diagnostic parameters and related mechanisms ...
The electrochem. oxidn. of phenol in the presence of NaCl for wastewater treatment was studied at Ti/SnO2 and Ti/IrO2 anodes. The presence of NaCl catalyzes the anodic oxidn. of phenol only at Ti/IrO2 anodes due to the participation of electrogenerated ClO ...
The electrochem. behavior of some model org. compds. on boron-doped synthetic diamond thin film electrodes, obtained by HF-CVD on p-Si substrate was investigated. Only reactions involving simple electron transfer like hydroquinone/benzoquinone are active i ...
The objectives of this study were to validate new experimental techniques used to measure the log P of protonated drugs, and to investigate the inter- and intramolecular forces influencing the partitioning behavior of β-blockers in isotropic biphasic solve ...
