Electro-combustion of polyacrylates with boron-doped diamond anodes
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Diamond films with different levels of doping have been the subject of applications and fundamental research in electrochemistry, opening up a new branch known as the electrochemistry of diamond. The electrochemical properties of diamond mostly depend on t ...
The electrochem. oxidn. of EDTA was studied at boron-doped diamond (BDD) electrodes. Cyclic voltammetry in the potential region of water stability showed that EDTA is oxidized in an irreversible 2-electron-transfer mechanism. No fouling phenomena were noti ...
A new parameter, the normalized current efficiency for the electro-combustion has been considered. This parameter allows to eliminate the mass transfer inefficiency and then can be defined as the ability of the anode to promote the electro-oxidn. and to re ...
Electrochem. oxidn. of orgs. at thermally prepd. dimensionally stable metal oxide anodes (DSA) has been studied. In reactions involving only simple electron transfer, oxide electrodes exhibit an electrocatalytic activity similar to that of noble metal elec ...
The electrochem. behavior of PbO2 and synthetic B-doped diamond thin film electrodes (BDDs) was studied in acid media contg. 4-chlorophenol (4-CP) by bulk electrolysis under different exptl. conditions. To quantify the electrochem. activity of a given elec ...
The aim was to examine the anodic oxidn. of some benzene derivs. (model org. pollutants) at Pt and DSA (dimensionally stable anodes) type anodes to elucidate the possibilities of the electrochem. method and to elucidate the mechanism of the reaction. ...
The anodic oxidn. of 2-naphthol in acid media was studied at a synthetic boron-doped diamond thin film electrode (BDD) using cyclic voltammetry and bulk electrolysis. The results showed that in the potential region, where the supporting electrolyte is stab ...
The electrochem. oxidn. (or combustion) of orgs. with simultaneous oxygen evolution has been investigated using different oxide electrodes. A simplified mechanism for the electrochem. oxidn. of orgs. is presented, according to which selective oxidn. occurs ...
A dimensionally stable anode with enhanced durability for use in electrochem. processes (e.g. those involving evolution of Cl2 or O2) is described. The anode consists of a substrate of >=1 metals or metal oxides provided with an outer Ta surface coated wit ...
(Electricite De France Service National, Fr.).1997
The electrochem. oxidn. (or combustion) of orgs. with simultaneous oxygen evolution was studied using different electrode materials (Ti/IrO2, Ti/SnO2). A simplified mechanism for the electrochem. oxidn. of orgs. is presented, according to which selective o ...